Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell
A model of reversible and quasi-reversible electrode reaction of dissolved redox couple is developed for the staircase voltammetry and the twin electrode thin layer cell. It is assumed that the neutral molecule is oxidized to a monovalent cation. The calculations were performed for the absence of su...
| Main Author: | |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Association of Physical Chemists (IAPC)
2019-12-01
|
| Series: | Journal of Electrochemical Science and Engineering |
| Subjects: | |
| Online Access: | http://pub.iapchem.org/ojs/index.php/JESE/article/view/713 |
| _version_ | 1811248176292691968 |
|---|---|
| author | Milivoj Lovrić |
| author_facet | Milivoj Lovrić |
| author_sort | Milivoj Lovrić |
| collection | DOAJ |
| description | A model of reversible and quasi-reversible electrode reaction of dissolved redox couple is developed for the staircase voltammetry and the twin electrode thin layer cell. It is assumed that the neutral molecule is oxidized to a monovalent cation. The calculations were performed for the absence of supporting electrolyte and for its various concentrations. The influence of migration of cations and of IRΩ drop on the peak currents and peak potentials was investigated. Also, the kinetically controlled electrode reactions were simulated. These reactions can be distinguished from the reactions influenced by the resistance in the solution. |
| first_indexed | 2024-04-12T15:22:25Z |
| format | Article |
| id | doaj.art-1d53a59589e14a85aa079e923ae3ad89 |
| institution | Directory Open Access Journal |
| issn | 1847-9286 |
| language | English |
| last_indexed | 2024-04-12T15:22:25Z |
| publishDate | 2019-12-01 |
| publisher | International Association of Physical Chemists (IAPC) |
| record_format | Article |
| series | Journal of Electrochemical Science and Engineering |
| spelling | doaj.art-1d53a59589e14a85aa079e923ae3ad892022-12-22T03:27:22ZengInternational Association of Physical Chemists (IAPC)Journal of Electrochemical Science and Engineering1847-92862019-12-0110110.5599/jese.713389Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cellMilivoj Lovrić0Divkovićeva 13, Zagreb 10090A model of reversible and quasi-reversible electrode reaction of dissolved redox couple is developed for the staircase voltammetry and the twin electrode thin layer cell. It is assumed that the neutral molecule is oxidized to a monovalent cation. The calculations were performed for the absence of supporting electrolyte and for its various concentrations. The influence of migration of cations and of IRΩ drop on the peak currents and peak potentials was investigated. Also, the kinetically controlled electrode reactions were simulated. These reactions can be distinguished from the reactions influenced by the resistance in the solution.http://pub.iapchem.org/ojs/index.php/JESE/article/view/713Staircase voltammetryThin layer cellMigrationTheory |
| spellingShingle | Milivoj Lovrić Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell Journal of Electrochemical Science and Engineering Staircase voltammetry Thin layer cell Migration Theory |
| title | Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell |
| title_full | Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell |
| title_fullStr | Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell |
| title_full_unstemmed | Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell |
| title_short | Staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell |
| title_sort | staircase voltammetry of dissolved redox couple in a thin layer twin electrode cell |
| topic | Staircase voltammetry Thin layer cell Migration Theory |
| url | http://pub.iapchem.org/ojs/index.php/JESE/article/view/713 |
| work_keys_str_mv | AT milivojlovric staircasevoltammetryofdissolvedredoxcoupleinathinlayertwinelectrodecell |