Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform
The crystal structure has a great influence on mechanical sensitivity and detonation performance of energetic materials. An efficient microfluidic platform was applied for size, morphology, and crystallinity controllable preparation of ultrafine HMX. The microfluidic platform has good mixing perform...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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MDPI AG
2023-01-01
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| Series: | Nanomaterials |
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| Online Access: | https://www.mdpi.com/2079-4991/13/3/464 |
| _version_ | 1827759675198668800 |
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| author | Hanyu Jiang Xuanjun Wang Jin Yu Wenjun Zhou Shuangfei Zhao Siyu Xu Fengqi Zhao |
| author_facet | Hanyu Jiang Xuanjun Wang Jin Yu Wenjun Zhou Shuangfei Zhao Siyu Xu Fengqi Zhao |
| author_sort | Hanyu Jiang |
| collection | DOAJ |
| description | The crystal structure has a great influence on mechanical sensitivity and detonation performance of energetic materials. An efficient microfluidic platform was applied for size, morphology, and crystallinity controllable preparation of ultrafine HMX. The microfluidic platform has good mixing performance, quick response, and less reagent consumption. The ultrafine γ-HMX was first prepared at room temperature by microfluidic strategy, and the crystal type can be controlled accurately by adjusting the process parameters. With the increase in flow ratio, the particle size decreases gradually, and the crystal type changed from β-HMX to γ-HMX. Thermal behavior of ultrafine HMX shows that γ→δ is easier than β→δ, and the phase stability of HMX is β > γ > δ. Furthermore, the ultrafine β-HMX has higher thermal stability and energy release efficiency than that of raw HMX. The ultrafine HMX prepared by microfluidic not only has uniform morphology and narrow particle size distribution, but also exhibits high density and low sensitivity. This study provides a safe, facile, and efficient way of controlling particle size, morphology, and crystallinity of ultrafine HMX. |
| first_indexed | 2024-03-11T09:31:04Z |
| format | Article |
| id | doaj.art-1d558983e68945fc9efd7257b723c8cf |
| institution | Directory Open Access Journal |
| issn | 2079-4991 |
| language | English |
| last_indexed | 2024-03-11T09:31:04Z |
| publishDate | 2023-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Nanomaterials |
| spelling | doaj.art-1d558983e68945fc9efd7257b723c8cf2023-11-16T17:35:06ZengMDPI AGNanomaterials2079-49912023-01-0113346410.3390/nano13030464Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic PlatformHanyu Jiang0Xuanjun Wang1Jin Yu2Wenjun Zhou3Shuangfei Zhao4Siyu Xu5Fengqi Zhao6Missile Engineering College, Rocket Force University of Engineering, Xi’an 710025, ChinaMissile Engineering College, Rocket Force University of Engineering, Xi’an 710025, ChinaScience and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Xi’an 710065, ChinaMissile Engineering College, Rocket Force University of Engineering, Xi’an 710025, ChinaCollege of Biotechnology and Pharmaceutical Engineering, Nanjing Tech University, Nanjing 211816, ChinaScience and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Xi’an 710065, ChinaScience and Technology on Combustion and Explosion Laboratory, Xi’an Modern Chemistry Research Institute, Xi’an 710065, ChinaThe crystal structure has a great influence on mechanical sensitivity and detonation performance of energetic materials. An efficient microfluidic platform was applied for size, morphology, and crystallinity controllable preparation of ultrafine HMX. The microfluidic platform has good mixing performance, quick response, and less reagent consumption. The ultrafine γ-HMX was first prepared at room temperature by microfluidic strategy, and the crystal type can be controlled accurately by adjusting the process parameters. With the increase in flow ratio, the particle size decreases gradually, and the crystal type changed from β-HMX to γ-HMX. Thermal behavior of ultrafine HMX shows that γ→δ is easier than β→δ, and the phase stability of HMX is β > γ > δ. Furthermore, the ultrafine β-HMX has higher thermal stability and energy release efficiency than that of raw HMX. The ultrafine HMX prepared by microfluidic not only has uniform morphology and narrow particle size distribution, but also exhibits high density and low sensitivity. This study provides a safe, facile, and efficient way of controlling particle size, morphology, and crystallinity of ultrafine HMX.https://www.mdpi.com/2079-4991/13/3/464energetic materialmicrofluidiccontrollable preparationultrafine HMXthermal application performance |
| spellingShingle | Hanyu Jiang Xuanjun Wang Jin Yu Wenjun Zhou Shuangfei Zhao Siyu Xu Fengqi Zhao Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform Nanomaterials energetic material microfluidic controllable preparation ultrafine HMX thermal application performance |
| title | Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform |
| title_full | Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform |
| title_fullStr | Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform |
| title_full_unstemmed | Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform |
| title_short | Size, Morphology and Crystallinity Control Strategy of Ultrafine HMX by Microfluidic Platform |
| title_sort | size morphology and crystallinity control strategy of ultrafine hmx by microfluidic platform |
| topic | energetic material microfluidic controllable preparation ultrafine HMX thermal application performance |
| url | https://www.mdpi.com/2079-4991/13/3/464 |
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