trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)

In the title compound, [Mn(C10H6N3O4)2(H2O)2], synthesized by hydrothermal reaction, the MnII ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two...

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Main Author: Li-Zhuang Chen
Format: Article
Language:English
Published: International Union of Crystallography 2008-10-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808029073
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author Li-Zhuang Chen
author_facet Li-Zhuang Chen
author_sort Li-Zhuang Chen
collection DOAJ
description In the title compound, [Mn(C10H6N3O4)2(H2O)2], synthesized by hydrothermal reaction, the MnII ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water molecules. A two-dimensional supramolecular architecture is formed via N—H...O, O—H...N and O—H...O hydrogen-bonding interactions.
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spelling doaj.art-1d58df30f2954f30a35b8b74f95429bc2022-12-21T18:41:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-10-016410m1286m128610.1107/S1600536808029073trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)Li-Zhuang ChenIn the title compound, [Mn(C10H6N3O4)2(H2O)2], synthesized by hydrothermal reaction, the MnII ion lies on an inversion centre and displays a distorted octahedral coordination geometry defined by the two imidazole N atoms and two carboxylate O atoms of the two trans-standing chelate ligands, and two O atoms of the water molecules. A two-dimensional supramolecular architecture is formed via N—H...O, O—H...N and O—H...O hydrogen-bonding interactions.http://scripts.iucr.org/cgi-bin/paper?S1600536808029073
spellingShingle Li-Zhuang Chen
trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)
Acta Crystallographica Section E
title trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)
title_full trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)
title_fullStr trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)
title_full_unstemmed trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)
title_short trans-Diaquabis[5-carboxy-2-(3-pyridyl)-1H-imidazole-4-carboxylato-κ2N3,O4]manganese(II)
title_sort trans diaquabis 5 carboxy 2 3 pyridyl 1h imidazole 4 carboxylato 954 2n3 o4 manganese ii
url http://scripts.iucr.org/cgi-bin/paper?S1600536808029073
work_keys_str_mv AT lizhuangchen transdiaquabis5carboxy23pyridyl1himidazole4carboxylato9542n3o4manganeseii