A Schmidt Decomposition Approach to Quantum Thermodynamics

The development of a self-consistent thermodynamic theory of quantum systems is of fundamental importance for modern physics. Still, despite its essential role in quantum science and technology, there is no unifying formalism for characterizing the thermodynamics within general autonomous quantum sy...

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Main Authors: André Hernandes Alves Malavazi, Frederico Brito
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Entropy
Subjects:
Online Access:https://www.mdpi.com/1099-4300/24/11/1645
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author André Hernandes Alves Malavazi
Frederico Brito
author_facet André Hernandes Alves Malavazi
Frederico Brito
author_sort André Hernandes Alves Malavazi
collection DOAJ
description The development of a self-consistent thermodynamic theory of quantum systems is of fundamental importance for modern physics. Still, despite its essential role in quantum science and technology, there is no unifying formalism for characterizing the thermodynamics within general autonomous quantum systems, and many fundamental open questions remain unanswered. Along these lines, most current efforts and approaches restrict the analysis to particular scenarios of approximative descriptions and semi-classical regimes. Here, we propose a novel approach to describe the thermodynamics of arbitrary bipartite autonomous quantum systems based on the well-known Schmidt decomposition. This formalism provides a simple, exact, and symmetrical framework for expressing the energetics between interacting systems, including scenarios beyond the standard description regimes, such as strong coupling. We show that this procedure allows straightforward identification of local effective operators suitable for characterizing the physical local internal energies. We also demonstrate that these quantities naturally satisfy the usual thermodynamic notion of energy additivity.
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spelling doaj.art-1dd24fce23d84839bb750f4a2ffcd78a2023-11-24T08:18:32ZengMDPI AGEntropy1099-43002022-11-012411164510.3390/e24111645A Schmidt Decomposition Approach to Quantum ThermodynamicsAndré Hernandes Alves Malavazi0Frederico Brito1Instituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, São Carlos 13560-970, SP, BrazilInstituto de Física de São Carlos, Universidade de São Paulo, C.P. 369, São Carlos 13560-970, SP, BrazilThe development of a self-consistent thermodynamic theory of quantum systems is of fundamental importance for modern physics. Still, despite its essential role in quantum science and technology, there is no unifying formalism for characterizing the thermodynamics within general autonomous quantum systems, and many fundamental open questions remain unanswered. Along these lines, most current efforts and approaches restrict the analysis to particular scenarios of approximative descriptions and semi-classical regimes. Here, we propose a novel approach to describe the thermodynamics of arbitrary bipartite autonomous quantum systems based on the well-known Schmidt decomposition. This formalism provides a simple, exact, and symmetrical framework for expressing the energetics between interacting systems, including scenarios beyond the standard description regimes, such as strong coupling. We show that this procedure allows straightforward identification of local effective operators suitable for characterizing the physical local internal energies. We also demonstrate that these quantities naturally satisfy the usual thermodynamic notion of energy additivity.https://www.mdpi.com/1099-4300/24/11/1645quantum thermodynamicsopen quantum systemsstrong coupling
spellingShingle André Hernandes Alves Malavazi
Frederico Brito
A Schmidt Decomposition Approach to Quantum Thermodynamics
Entropy
quantum thermodynamics
open quantum systems
strong coupling
title A Schmidt Decomposition Approach to Quantum Thermodynamics
title_full A Schmidt Decomposition Approach to Quantum Thermodynamics
title_fullStr A Schmidt Decomposition Approach to Quantum Thermodynamics
title_full_unstemmed A Schmidt Decomposition Approach to Quantum Thermodynamics
title_short A Schmidt Decomposition Approach to Quantum Thermodynamics
title_sort schmidt decomposition approach to quantum thermodynamics
topic quantum thermodynamics
open quantum systems
strong coupling
url https://www.mdpi.com/1099-4300/24/11/1645
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