N′-[(E)-2-Fluorobenzylidene]benzohydrazide
The asymmetric unit of the title compound, C14H11FN2O, contains two independent molecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The molecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11)° between the benzene...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813031747 |
| _version_ | 1818974137872285696 |
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| author | M. R. Prathapachandra Kurup N. Aiswarya M. Sithambaresan P. B. Sreeja |
| author_facet | M. R. Prathapachandra Kurup N. Aiswarya M. Sithambaresan P. B. Sreeja |
| author_sort | M. R. Prathapachandra Kurup |
| collection | DOAJ |
| description | The asymmetric unit of the title compound, C14H11FN2O, contains two independent molecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The molecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11)° between the benzene and phenyl rings. In the crystal, molecules are linked through N—H...O=C and N—H...N hydrogen bonds into chains along [101]. C—H...O contacts link these chains into layers parallel to (001). The three-dimensional crystal packing is stabilized by π–π interactions, the shortest separation between the centroids of benzene rings being 3.884 (1) Å. |
| first_indexed | 2024-12-20T15:35:17Z |
| format | Article |
| id | doaj.art-1dd46cb250ed47f7acd9ded04ef55de8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:35:17Z |
| publishDate | 2013-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1dd46cb250ed47f7acd9ded04ef55de82022-12-21T19:35:26ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-12-016912o1828o182810.1107/S1600536813031747N′-[(E)-2-Fluorobenzylidene]benzohydrazideM. R. Prathapachandra KurupN. AiswaryaM. SithambaresanP. B. SreejaThe asymmetric unit of the title compound, C14H11FN2O, contains two independent molecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The molecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11)° between the benzene and phenyl rings. In the crystal, molecules are linked through N—H...O=C and N—H...N hydrogen bonds into chains along [101]. C—H...O contacts link these chains into layers parallel to (001). The three-dimensional crystal packing is stabilized by π–π interactions, the shortest separation between the centroids of benzene rings being 3.884 (1) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536813031747 |
| spellingShingle | M. R. Prathapachandra Kurup N. Aiswarya M. Sithambaresan P. B. Sreeja N′-[(E)-2-Fluorobenzylidene]benzohydrazide Acta Crystallographica Section E |
| title | N′-[(E)-2-Fluorobenzylidene]benzohydrazide |
| title_full | N′-[(E)-2-Fluorobenzylidene]benzohydrazide |
| title_fullStr | N′-[(E)-2-Fluorobenzylidene]benzohydrazide |
| title_full_unstemmed | N′-[(E)-2-Fluorobenzylidene]benzohydrazide |
| title_short | N′-[(E)-2-Fluorobenzylidene]benzohydrazide |
| title_sort | n 8242 e 2 fluorobenzylidene benzohydrazide |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813031747 |
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