Crystal structure of strontium thiosulfate monohydrate
SrS2O3·H2O was obtained from an aqueous solution of Na2S2O3 and Sr(NO3)2 and crystallizes in space group P\overline{1} with all atoms at general positions. The Sr2+ ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the latter at a longer dista...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-02-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989020000353 |
| _version_ | 1819278234045382656 |
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| author | Wilhelm Klein |
| author_facet | Wilhelm Klein |
| author_sort | Wilhelm Klein |
| collection | DOAJ |
| description | SrS2O3·H2O was obtained from an aqueous solution of Na2S2O3 and Sr(NO3)2 and crystallizes in space group P\overline{1} with all atoms at general positions. The Sr2+ ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the latter at a longer distance, and by one O atom of a water molecule. Two thiosulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically interacting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H...S and O—H...O hydrogen bonds of moderate strength. |
| first_indexed | 2024-12-24T00:08:46Z |
| format | Article |
| id | doaj.art-1dd67b0e9f494c04a762f3ca94a88676 |
| institution | Directory Open Access Journal |
| issn | 2056-9890 |
| language | English |
| last_indexed | 2024-12-24T00:08:46Z |
| publishDate | 2020-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj.art-1dd67b0e9f494c04a762f3ca94a886762022-12-21T17:24:56ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902020-02-0176219720010.1107/S2056989020000353wm5535Crystal structure of strontium thiosulfate monohydrateWilhelm Klein0Technische Universität München, Department of Chemistry, Lichtenbergstr. 4, 85747 Garching, GermanySrS2O3·H2O was obtained from an aqueous solution of Na2S2O3 and Sr(NO3)2 and crystallizes in space group P\overline{1} with all atoms at general positions. The Sr2+ ion exhibits an [8 + 1] coordination defined by two terminal S and six O atoms of thiosulfate ions, one of the latter at a longer distance, and by one O atom of a water molecule. Two thiosulfate anions act as bidentate, four as monodentate ligands. The structure consists of mainly ionically interacting layers lying parallel to the crystallographic ab plane. The layers are connected by O—H...S and O—H...O hydrogen bonds of moderate strength.http://scripts.iucr.org/cgi-bin/paper?S2056989020000353crystal structurethiosulfatestrontiumhydratehydrogen bonding |
| spellingShingle | Wilhelm Klein Crystal structure of strontium thiosulfate monohydrate Acta Crystallographica Section E: Crystallographic Communications crystal structure thiosulfate strontium hydrate hydrogen bonding |
| title | Crystal structure of strontium thiosulfate monohydrate |
| title_full | Crystal structure of strontium thiosulfate monohydrate |
| title_fullStr | Crystal structure of strontium thiosulfate monohydrate |
| title_full_unstemmed | Crystal structure of strontium thiosulfate monohydrate |
| title_short | Crystal structure of strontium thiosulfate monohydrate |
| title_sort | crystal structure of strontium thiosulfate monohydrate |
| topic | crystal structure thiosulfate strontium hydrate hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2056989020000353 |
| work_keys_str_mv | AT wilhelmklein crystalstructureofstrontiumthiosulfatemonohydrate |