Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films

High-strength polyethylene films containing 0.5-1.0 wt. % of nanocrystalline silicon (nc-Si) were synthesized. Samples of nc-Si with an average core diameter of 7-10 nm were produced by plasmochemical method and by laser-induced decomposition of monosilane. Spectral studies revealed almost complete...

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Main Authors: Olkhov Anatoliy Aleksandrovich, Zaikov Gennady Efremovich
Format: Article
Language:English
Published: Volgograd State University 2014-12-01
Series:Vestnik Volgogradskogo Gosudarstvennogo Universiteta. Seriâ 10. Innovacionnaâ Deâtelʹnostʹ
Subjects:
Online Access:http://ti.jvolsu.com/index.php/en/component/attachments/download/347
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author Olkhov Anatoliy Aleksandrovich
Zaikov Gennady Efremovich
author_facet Olkhov Anatoliy Aleksandrovich
Zaikov Gennady Efremovich
author_sort Olkhov Anatoliy Aleksandrovich
collection DOAJ
description High-strength polyethylene films containing 0.5-1.0 wt. % of nanocrystalline silicon (nc-Si) were synthesized. Samples of nc-Si with an average core diameter of 7-10 nm were produced by plasmochemical method and by laser-induced decomposition of monosilane. Spectral studies revealed almost complete (up to ~95 %) absorption of UV radiation in 200- 400 nm spectral region by 85 micron thick film if the nc-Si content approaches to 1.0 wt. %. The density function of particle size in the starting powders and polymer films containing immobilized silicon nanocrystallites were obtained using the modeling a complete profile of X-ray diffraction patterns, assuming spherical grains and the lognormal distribution. The results of X-ray analysis shown that the crystallite size distribution function remains almost unchanged and the crystallinity of the original polymer increases to about 10 % with the implantation of the initial nc-Si samples in the polymer matrix.
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spelling doaj.art-1de9eaa41c984621a81b02d039d6c0432022-12-22T01:20:53ZengVolgograd State UniversityVestnik Volgogradskogo Gosudarstvennogo Universiteta. Seriâ 10. Innovacionnaâ Deâtelʹnostʹ2305-78152409-23982014-12-016637210.15688/jvolsu10.2014.6.6Nanocomposites Based on Polyethylene and Nanocrystalline Silicon FilmsOlkhov Anatoliy Aleksandrovich0Zaikov Gennady Efremovich1Lomonosov Moscow State University of Fine Chemical TechnologiesInstitute of Biochemical Physics named after N.M. Emanuel, RASHigh-strength polyethylene films containing 0.5-1.0 wt. % of nanocrystalline silicon (nc-Si) were synthesized. Samples of nc-Si with an average core diameter of 7-10 nm were produced by plasmochemical method and by laser-induced decomposition of monosilane. Spectral studies revealed almost complete (up to ~95 %) absorption of UV radiation in 200- 400 nm spectral region by 85 micron thick film if the nc-Si content approaches to 1.0 wt. %. The density function of particle size in the starting powders and polymer films containing immobilized silicon nanocrystallites were obtained using the modeling a complete profile of X-ray diffraction patterns, assuming spherical grains and the lognormal distribution. The results of X-ray analysis shown that the crystallite size distribution function remains almost unchanged and the crystallinity of the original polymer increases to about 10 % with the implantation of the initial nc-Si samples in the polymer matrix.http://ti.jvolsu.com/index.php/en/component/attachments/download/347polyethylenenanocrystalline siliconUV-protective filmpolymer nanocompositeshigh-strength films
spellingShingle Olkhov Anatoliy Aleksandrovich
Zaikov Gennady Efremovich
Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films
Vestnik Volgogradskogo Gosudarstvennogo Universiteta. Seriâ 10. Innovacionnaâ Deâtelʹnostʹ
polyethylene
nanocrystalline silicon
UV-protective film
polymer nanocomposites
high-strength films
title Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films
title_full Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films
title_fullStr Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films
title_full_unstemmed Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films
title_short Nanocomposites Based on Polyethylene and Nanocrystalline Silicon Films
title_sort nanocomposites based on polyethylene and nanocrystalline silicon films
topic polyethylene
nanocrystalline silicon
UV-protective film
polymer nanocomposites
high-strength films
url http://ti.jvolsu.com/index.php/en/component/attachments/download/347
work_keys_str_mv AT olkhovanatoliyaleksandrovich nanocompositesbasedonpolyethyleneandnanocrystallinesiliconfilms
AT zaikovgennadyefremovich nanocompositesbasedonpolyethyleneandnanocrystallinesiliconfilms