Summary: | Southeast Asia is one of the largest biomass burning (BB) regions in the world, and the air pollutants generated by this BB have an important impact on air pollution in southern China. However, the mechanism of the cross-border transport of BB pollutants to neighboring regions is yet to be understood. Based on the MODIS remote sensing products and conventional observation data of meteorology and the environment, the WRF-Chem and FLEXPART-WRF models were used to simulate a typical PM<sub>2.5</sub> pollution episode that occurred during 24–26 March 2017 to analyze the mechanism of cross-border transport of BB pollutants over Yunnan Plateau (YP) in southwest China. During this air pollution episode, in conjunction with the flourishing BB activities over the neighboring Indo-China Peninsula (ICP) regions in Southeast Asia, and driven by the southwesterly winds prevailing from the ICP to YP, the cross-border transport of pollutants was observed along the transport pathway with the lifting plateau topography in YP. Based on the proximity to the BB sources in ICP, YP was divided into a source region (SR) and a receptor region (RR) for the cross-border transport, and the negative and positive correlation coefficients (R) between PM<sub>2.5</sub> concentrations and wind speeds, respectively, were presented, indicating the different impacts of BB emissions on the two regions. XSBN and Kunming, the representative SR and RR sites in the border and hinterland of YP, respectively, have distinct mechanisms that enhance PM<sub>2.5</sub> concentrations of air pollution. The SR site is mainly affected by the ICP BB emissions with local accumulation in the stagnant meteorological conditions, whereas the RR site is dominated by the regional transport of PM<sub>2.5</sub> with strong winds and vertical mixing. It was revealed that the large PM<sub>2.5</sub> contributions of ICP BB emissions lift from the lower altitudes in SR to the higher altitudes in RR for the regional transport of PM<sub>2.5</sub>. Moreover, the contributions of regional transport of PM<sub>2.5</sub> decrease with the increase in transport distance, reflecting an important role of transport distance between the source–receptor areas in air pollution change.
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