Zn(II)-to-Cu(II) Transmetalation in an Amide Functionalized Complex and Catalytic Applications in Styrene Oxidation and Nitroaldol Coupling

Zn(II)-to-Cu(II) Transmetalation in an Amide Functionalized Complex and Catalytic Applications in Styrene Oxidation and Nitroaldol Coupling

The mononuclear zinc(II) complex <i>cis</i>-[ZnL<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>] (<b>1</b>; L = 4-(pyridin-3-ylcarbamoyl)benzoate) was synthesized and characterized. By soaking crystals of <b>1</b> in a mixture of DMF-H...

Full description

Bibliographic Details
Main Authors:	Anup Paul, Luísa M. D. R. S. Martins, Anirban Karmakar, Maxim L. Kuznetsov, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro
Format:	Article
Language:	English
Published:	MDPI AG 2020-06-01
Series:	Molecules
Subjects:	amide functionalized transmetalation DFT calculations oxidation of styrene nitroaldol
Online Access:	https://www.mdpi.com/1420-3049/25/11/2644

Similar Items

Copper-Catalyzed Homocoupling of Boronic Acids: A Focus on B-to-Cu and Cu-to-Cu Transmetalations
by: Aude Salamé, et al.
Published: (2022-11-01)

Transmetalation from Magnesium–NHCs—Convenient Synthesis of Chelating π-Acidic NHC Complexes
by: Julian Messelberger, et al.
Published: (2019-05-01)

Keratin Protein-Catalyzed Nitroaldol (Henry) Reaction and Comparison with Other Biopolymers
by: Marleen Häring, et al.
Published: (2016-08-01)

New Bioconjugated Technetium and Rhenium Folates Synthesized by Transmetallation Reaction with Zinc Derivatives
by: Jordi Borràs, et al.
Published: (2021-04-01)

K2CO3/PG DES promoted transition metal free room temperature synthesis of nitroaldols and nitroolefins
by: Parmita Phukan, et al.
Published: (2022-01-01)

Stereoselective formation of bismuth complexes by transmetalation of lead with adaptable overhanging carboxylic acid 5,10-strapped porphyrins
by: Barakat, Wael, et al.
Published: (2021-07-01)

Imaging of Transmetallation and Chelation Phenomena Involving Radiological Contrast Agents in Mineral-Rich Fruits
by: Subhendra Sarkar, et al.
Published: (2022-05-01)

Current Trends in the Synthesis of Practically Important Five-Membered Boracarbocycles by Transmetalation of Aluminacarbocycles with Boron Halides
by: Liliya I. Tulyabaeva, et al.
Published: (2022-11-01)

Reactions of the organoplatinum complex [Pt(cod) (neoSi)Cl] (neoSi = trimethylsilylmethyl) with the non-coordinating anions SbF6– and BPh4–
by: Neugebauer Michael, et al.
Published: (2018-11-01)

Synthesis of titanium containing aluminophosphate molecular sieve in catalytic oxidation of styrene /
by: Nurliana Roslan, 1988-, et al.
Published: (2012)

Nitrogen-Rich Tetrazole–Amide-Functionalised Zn Metal–Organic Framework as Catalyst for Efficient Catalytic CO<sub>2</sub> Cycloaddition with Epoxides
by: Anup Paul, et al.
Published: (2023-12-01)

Synthesis of 7,7,14,14-tetrachlorodinaphtho[1,8bc:1′,8′-fg][1,5]distannocine. Molecular structure of the di-water tetra-THF adduct
by: Beckmann Jens, et al.
Published: (2013-07-01)

Synthesis of titanium containing aluminophosphate molecular sieve in catalytic oxidation of styrene [electronic resource] /
by: Nurliana Roslan, 1988-
Published: (2012)

Styrene-based plastics and their modification /
by: Svec, Petr
Published: (1990)

Styrene and Azo-Styrene Based Colorimetric Sensors for Highly Selective Detection of Cyanide
by: Agustina Eka Prestiani, et al.
Published: (2017-07-01)

Synthetic and DFT Modeling Studies on Suzuki–Miyaura Reactions of 4,5-Dibromo-2-methylpyridazin-3(2<i>H</i>)-one with Ferrocene Boronates, Accompanied by Hydrodebromination and a Novel Bridge-Forming Annulation In Vitro Cytotoxic Activity of the Ferrocenyl–Pyridazinone Products
by: Nour-Eddine El Alaoui, et al.
Published: (2022-05-01)

Computational Study of Mechanism and Thermodynamics of Ni/IPr-Catalyzed Amidation of Esters
by: Chong-Lei Ji, et al.
Published: (2018-10-01)

Lurgi develops low energy route to styrene

Organocatalytic Enantioselective Henry Reactions
by: Raquel P. Herrera, et al.
Published: (2011-05-01)

Nitroalkanes as Central Reagents in the Synthesis of Spiroketals
by: Goffredo Rosini, et al.
Published: (2008-02-01)

Addition of boranes to (E)-(η5-C5H5)2Zr(CH=CHPh)Cl
by: Ferland Patrick, et al.
Published: (2013-05-01)

Degradation of styrene from petrochemical wastewater by PSEUDOMONAS SP. /
by: 285251 Pamela Baldwin Thomas
Published: (2007)

Styrene-butadiene copolymers - Determination of bound styrene content
by: 5087 International Organization for Standardization

Facile Amidation of Non-Protected Hydroxycinnamic Acids for the Synthesis of Natural Phenol Amides
by: Annemiek van Zadelhoff, et al.
Published: (2022-03-01)

Effect of styrene content on mechanical and rheological behavior of styrene butadiene rubber
by: Li’e Wang, et al.
Published: (2020-01-01)

Reactions of styrene and derivatives with sulfur trioxide ; characterization and chemistry of the initial products /
by: 438514 Schonk, Ruud M., et al.

Degradation of styrene from petrochemical wastewater by PSEUDOMONAS SP. [electronic resource] /
by: 285251 Pamela Baldwin Thomas
Published: (2007)

Effects of organoclay and styrene - (Ethylene - co - Butene) - styrene on the morphology, mechanical and physical properties of polyamide 6/polystyrene nanocomposites /
by: 300994 Norshafini Mohd. Zain, et al.
Published: (2007)

Rubber - reinforced styrene-butadiene latex - determination of total bound styrene content
by: 5087 International Organization for Standardization

Selective oxidation improves styrene process economics

Microwave-Assisted Catalytic Method for a Green Synthesis of Amides Directly from Amines and Carboxylic Acids
by: Adam P. Zarecki, et al.
Published: (2020-04-01)

Rubber latex - Styrene-butadiene - Determination of bound styrene content
by: 5087 International Organization for Standardization

Pengaruh Konsentrasi Inisiator Dan Komposisi Styrene Dan Maleic Anhydride Terhadap Berat Molekul Pada Sintesis Kopolimer Poly (Styrene-Maleic Anhydride)
by: Bambang Afrinaldi, et al.
Published: (2014-10-01)

Hydrotelluration of alkynes: a unique route to Z-vinyl organometallics
by: Vieira Maurício L., et al.
Published: (2001-01-01)

Packaging Materials Based on Styrene-Isoprene-Styrene Triblock Copolymer Modified with Graphene
by: Traian Zaharescu, et al.
Published: (2023-01-01)

The Impact of AN Contribution on the Thermal Characteristics and Molecular Dynamics of Novel Acrylonitrile–Styrene–Styrene Sodium Sulfonate Terpolymers
by: Hamud A. Altaleb, et al.
Published: (2021-01-01)

In search of selectivity in oxidation of styrene by titanium-loaded zeolite particles wiyh different location of titanium active sites and hydrophobicity /
by: 330168 Nur Hajarul Aswani Moamail, et al.
Published: (2007)

Rubber - Determination of styrene content - Nitration method
by: 5087 International Organization for Standardization

An Insight into the Growing Concerns of Styrene Monomer and Poly(Styrene) Fragment Migration into Food and Drink Simulants from Poly(Styrene) Packaging
by: Asmaa Ajaj, et al.
Published: (2021-05-01)

Experimental Study of Tensile Properties of Styrene–Butadiene–Styrene Modified Asphalt Binders
by: Paweł Mieczkowski, et al.
Published: (2021-04-01)