Simulation of electrical conductivity for polymer silver nanowires systems

Abstract A simple model is developed for the conductivity of polymeric systems including silver nanowires (AgNWs). This model reveals the effects of interphase thickness, tunneling distance, waviness and aspect ratio of nanowires, as well as effective filler volume fraction on the percolation and el...

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Main Authors: Ali Mohammadpour-Haratbar, Yasser Zare, Kyong Yop Rhee
Format: Article
Language:English
Published: Nature Portfolio 2023-01-01
Series:Scientific Reports
Online Access:https://doi.org/10.1038/s41598-022-25548-w
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author Ali Mohammadpour-Haratbar
Yasser Zare
Kyong Yop Rhee
author_facet Ali Mohammadpour-Haratbar
Yasser Zare
Kyong Yop Rhee
author_sort Ali Mohammadpour-Haratbar
collection DOAJ
description Abstract A simple model is developed for the conductivity of polymeric systems including silver nanowires (AgNWs). This model reveals the effects of interphase thickness, tunneling distance, waviness and aspect ratio of nanowires, as well as effective filler volume fraction on the percolation and electrical conductivity of AgNW-reinforced samples. The validity of this model is tested by using the measured data from several samples. Based on this model, the conductivity calculations are in proper accordance with the measured values. A large network and a low percolation onset are produced by nanowires with a high aspect ratio developing the nanocomposite conductivity. The results also show that a thicker interphase expands the network, thereby increasing the electrical conductivity. Furthermore, non-waved AgNWs exhibit more conductivity compared to wavy nanowires. It is concluded that the surface energies of polymer medium and nanowires have no effect on the conductivity of samples. On the other hand, the volume fraction and aspect ratio of nanowires, in addition to the interphase thickness and tunneling distance have the greatest influences on the conductivity of nanocomposites.
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spelling doaj.art-1e265b479e5b4f5faf8b7959b012b84e2023-01-08T12:11:13ZengNature PortfolioScientific Reports2045-23222023-01-0113111110.1038/s41598-022-25548-wSimulation of electrical conductivity for polymer silver nanowires systemsAli Mohammadpour-Haratbar0Yasser Zare1Kyong Yop Rhee2Biomaterials and Tissue Engineering Research Group, Department of Interdisciplinary Technologies, Breast Cancer Research Center, Motamed Cancer Institute, ACECRBiomaterials and Tissue Engineering Research Group, Department of Interdisciplinary Technologies, Breast Cancer Research Center, Motamed Cancer Institute, ACECRDepartment of Mechanical Engineering (BK21 Four), College of Engineering, Kyung Hee UniversityAbstract A simple model is developed for the conductivity of polymeric systems including silver nanowires (AgNWs). This model reveals the effects of interphase thickness, tunneling distance, waviness and aspect ratio of nanowires, as well as effective filler volume fraction on the percolation and electrical conductivity of AgNW-reinforced samples. The validity of this model is tested by using the measured data from several samples. Based on this model, the conductivity calculations are in proper accordance with the measured values. A large network and a low percolation onset are produced by nanowires with a high aspect ratio developing the nanocomposite conductivity. The results also show that a thicker interphase expands the network, thereby increasing the electrical conductivity. Furthermore, non-waved AgNWs exhibit more conductivity compared to wavy nanowires. It is concluded that the surface energies of polymer medium and nanowires have no effect on the conductivity of samples. On the other hand, the volume fraction and aspect ratio of nanowires, in addition to the interphase thickness and tunneling distance have the greatest influences on the conductivity of nanocomposites.https://doi.org/10.1038/s41598-022-25548-w
spellingShingle Ali Mohammadpour-Haratbar
Yasser Zare
Kyong Yop Rhee
Simulation of electrical conductivity for polymer silver nanowires systems
Scientific Reports
title Simulation of electrical conductivity for polymer silver nanowires systems
title_full Simulation of electrical conductivity for polymer silver nanowires systems
title_fullStr Simulation of electrical conductivity for polymer silver nanowires systems
title_full_unstemmed Simulation of electrical conductivity for polymer silver nanowires systems
title_short Simulation of electrical conductivity for polymer silver nanowires systems
title_sort simulation of electrical conductivity for polymer silver nanowires systems
url https://doi.org/10.1038/s41598-022-25548-w
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AT yasserzare simulationofelectricalconductivityforpolymersilvernanowiressystems
AT kyongyoprhee simulationofelectricalconductivityforpolymersilvernanowiressystems