Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics

Compounds emitted during thermo-oxidative decomposition of three commercial polyester fabrics for indoor outfit and decorations (upholstery, curtains) were studied. The experiments were carried out in a flow tubular furnace at 600°C in an air atmosphere. During decomposition process the complex mixt...

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Main Authors: Dzięcioł Małgorzata, Huzar Elżbieta
Format: Article
Language:English
Published: Sciendo 2016-03-01
Series:Polish Journal of Chemical Technology
Subjects:
Online Access:https://doi.org/10.1515/pjct-2016-0007
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author Dzięcioł Małgorzata
Huzar Elżbieta
author_facet Dzięcioł Małgorzata
Huzar Elżbieta
author_sort Dzięcioł Małgorzata
collection DOAJ
description Compounds emitted during thermo-oxidative decomposition of three commercial polyester fabrics for indoor outfit and decorations (upholstery, curtains) were studied. The experiments were carried out in a flow tubular furnace at 600°C in an air atmosphere. During decomposition process the complex mixtures of volatile and solid compounds were emitted. The main volatile products were carbon oxides, benzene, acetaldehyde, vinyl benzoate and acetophe-none. The emitted solid compounds consisted mainly of aromatic carboxylic acids and its derivatives, among which the greatest part took terephthalic acid, monovinyl terephthalate and benzoic acid. The small amounts of polycyclic aromatic hydrocarbons were also emitted. The emission profiles of the tested polyester fabrics were similar. The presence of toxic compounds indicates the possibility of serious hazard for people during fire.
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spelling doaj.art-1e2b5497660544418f43168289f8e8d62022-12-21T22:48:27ZengSciendoPolish Journal of Chemical Technology1899-47412016-03-01181404510.1515/pjct-2016-0007pjct-2016-0007Study of compounds emitted during thermo-oxidative decomposition of polyester fabricsDzięcioł Małgorzata0Huzar Elżbieta1West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, al. Piastów 42, 71-065 Szczecin, PolandWest Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, al. Piastów 42, 71-065 Szczecin, PolandCompounds emitted during thermo-oxidative decomposition of three commercial polyester fabrics for indoor outfit and decorations (upholstery, curtains) were studied. The experiments were carried out in a flow tubular furnace at 600°C in an air atmosphere. During decomposition process the complex mixtures of volatile and solid compounds were emitted. The main volatile products were carbon oxides, benzene, acetaldehyde, vinyl benzoate and acetophe-none. The emitted solid compounds consisted mainly of aromatic carboxylic acids and its derivatives, among which the greatest part took terephthalic acid, monovinyl terephthalate and benzoic acid. The small amounts of polycyclic aromatic hydrocarbons were also emitted. The emission profiles of the tested polyester fabrics were similar. The presence of toxic compounds indicates the possibility of serious hazard for people during fire.https://doi.org/10.1515/pjct-2016-0007polyester fabricspoly(ethylene terephthalate)thermo-oxidative decomposition of polyesterscombustion of polyesters
spellingShingle Dzięcioł Małgorzata
Huzar Elżbieta
Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics
Polish Journal of Chemical Technology
polyester fabrics
poly(ethylene terephthalate)
thermo-oxidative decomposition of polyesters
combustion of polyesters
title Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics
title_full Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics
title_fullStr Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics
title_full_unstemmed Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics
title_short Study of compounds emitted during thermo-oxidative decomposition of polyester fabrics
title_sort study of compounds emitted during thermo oxidative decomposition of polyester fabrics
topic polyester fabrics
poly(ethylene terephthalate)
thermo-oxidative decomposition of polyesters
combustion of polyesters
url https://doi.org/10.1515/pjct-2016-0007
work_keys_str_mv AT dzieciołmałgorzata studyofcompoundsemittedduringthermooxidativedecompositionofpolyesterfabrics
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