Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys

Copper is a key material for cooling of thermally stressed components in modern aerospace propulsion systems, due to its high thermal conductivity. The use of copper materials for such applications requires both high material strength and high stability at high temperatures, which can be achieved by...

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Main Authors: Markus B. Wilms, Silja-Katharina Rittinghaus
Format: Article
Language:English
Published: MDPI AG 2022-09-01
Series:Journal of Manufacturing and Materials Processing
Subjects:
Online Access:https://www.mdpi.com/2504-4494/6/5/102
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author Markus B. Wilms
Silja-Katharina Rittinghaus
author_facet Markus B. Wilms
Silja-Katharina Rittinghaus
author_sort Markus B. Wilms
collection DOAJ
description Copper is a key material for cooling of thermally stressed components in modern aerospace propulsion systems, due to its high thermal conductivity. The use of copper materials for such applications requires both high material strength and high stability at high temperatures, which can be achieved by the concept of oxide dispersion strengthening. In the present work, we demonstrate the oxide reinforcement of two highly conductive precipitation-strengthened Cu-Cr-Nb alloys using laser additive manufacturing. Gas-atomized Cu-3.3Cr-0.5Nb and Cu-3.3Cr-1.5Nb (wt.%) powder materials are decorated with Y<sub>2</sub>O<sub>3</sub> nanoparticles by mechanical alloying in a planetary mill and followed by consolidation by the laser additive manufacturing process of laser powder bed fusion (L-PBF). While dense specimens (>99.5%) of reinforced and nonreinforced alloys can be manufactured, oxide dispersion-strengthened alloys additionally exhibit homogeneously distributed oxide nanoparticles enriched in yttrium and chromium next to Cr<sub>2</sub>Nb precipitates present in all alloys examined. Higher niobium contents result in moderate increase of the Vickers hardness of approx. 10 HV0.3, while the homogeneously dispersed nanometer-sized oxide particles lead to a pronounced increase of approx. 30 HV0.3 in material strength compared to their nonreinforced counterparts.
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spelling doaj.art-1e2b9d4e61bd477084da8afad681352e2023-11-24T00:42:15ZengMDPI AGJournal of Manufacturing and Materials Processing2504-44942022-09-016510210.3390/jmmp6050102Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium AlloysMarkus B. Wilms0Silja-Katharina Rittinghaus1Chair of Materials Science and Additive Manufacturing, School of Mechanical Engineering and Safety Engineering, University of Wuppertal, Gaussstr. 20, 42119 Wuppertal, GermanyChair of Materials Science and Additive Manufacturing, School of Mechanical Engineering and Safety Engineering, University of Wuppertal, Gaussstr. 20, 42119 Wuppertal, GermanyCopper is a key material for cooling of thermally stressed components in modern aerospace propulsion systems, due to its high thermal conductivity. The use of copper materials for such applications requires both high material strength and high stability at high temperatures, which can be achieved by the concept of oxide dispersion strengthening. In the present work, we demonstrate the oxide reinforcement of two highly conductive precipitation-strengthened Cu-Cr-Nb alloys using laser additive manufacturing. Gas-atomized Cu-3.3Cr-0.5Nb and Cu-3.3Cr-1.5Nb (wt.%) powder materials are decorated with Y<sub>2</sub>O<sub>3</sub> nanoparticles by mechanical alloying in a planetary mill and followed by consolidation by the laser additive manufacturing process of laser powder bed fusion (L-PBF). While dense specimens (>99.5%) of reinforced and nonreinforced alloys can be manufactured, oxide dispersion-strengthened alloys additionally exhibit homogeneously distributed oxide nanoparticles enriched in yttrium and chromium next to Cr<sub>2</sub>Nb precipitates present in all alloys examined. Higher niobium contents result in moderate increase of the Vickers hardness of approx. 10 HV0.3, while the homogeneously dispersed nanometer-sized oxide particles lead to a pronounced increase of approx. 30 HV0.3 in material strength compared to their nonreinforced counterparts.https://www.mdpi.com/2504-4494/6/5/102oxide dispersion strengtheningODScopper–chromium–niobiumlaser additive manufacturinglaser powder bed fusion
spellingShingle Markus B. Wilms
Silja-Katharina Rittinghaus
Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys
Journal of Manufacturing and Materials Processing
oxide dispersion strengthening
ODS
copper–chromium–niobium
laser additive manufacturing
laser powder bed fusion
title Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys
title_full Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys
title_fullStr Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys
title_full_unstemmed Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys
title_short Laser Additive Manufacturing of Oxide Dispersion-Strengthened Copper–Chromium–Niobium Alloys
title_sort laser additive manufacturing of oxide dispersion strengthened copper chromium niobium alloys
topic oxide dispersion strengthening
ODS
copper–chromium–niobium
laser additive manufacturing
laser powder bed fusion
url https://www.mdpi.com/2504-4494/6/5/102
work_keys_str_mv AT markusbwilms laseradditivemanufacturingofoxidedispersionstrengthenedcopperchromiumniobiumalloys
AT siljakatharinarittinghaus laseradditivemanufacturingofoxidedispersionstrengthenedcopperchromiumniobiumalloys