Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses

The polarization properties of bismuth active centers (BACs) are important for many applications of bismuth-doped fibers, but they are still lacking in study. In this paper, we present the measurements of polarized luminescence (PL) of the BACs formed in a Bi-doped phosphosilicate glass matrix. This...

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Main Authors: Alexander V. Elopov, Konstantin E. Riumkin, Fedor V. Afanasiev, Sergey V. Alyshev, Alexander V. Kharakhordin, Aleksandr M. Khegai, Elena G. Firstova, Sergei V. Firstov, Konstantin N. Nishchev, Mikhail A. Melkumov
Format: Article
Language:English
Published: MDPI AG 2023-07-01
Series:Photonics
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Online Access:https://www.mdpi.com/2304-6732/10/8/860
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author Alexander V. Elopov
Konstantin E. Riumkin
Fedor V. Afanasiev
Sergey V. Alyshev
Alexander V. Kharakhordin
Aleksandr M. Khegai
Elena G. Firstova
Sergei V. Firstov
Konstantin N. Nishchev
Mikhail A. Melkumov
author_facet Alexander V. Elopov
Konstantin E. Riumkin
Fedor V. Afanasiev
Sergey V. Alyshev
Alexander V. Kharakhordin
Aleksandr M. Khegai
Elena G. Firstova
Sergei V. Firstov
Konstantin N. Nishchev
Mikhail A. Melkumov
author_sort Alexander V. Elopov
collection DOAJ
description The polarization properties of bismuth active centers (BACs) are important for many applications of bismuth-doped fibers, but they are still lacking in study. In this paper, we present the measurements of polarized luminescence (PL) of the BACs formed in a Bi-doped phosphosilicate glass matrix. This research was performed on phosphosilicate fiber preforms used for the drawing of active bismuth-doped fibers for efficient optical amplifiers and lasers. The degree of polarization (DOP) of luminescence of the BACs associated with phosphorus and silica (BAC-P and BAC-Si) is provided and discussed. The DOP of luminescence at the 1320 nm wavelength appeared to be around 19%, 0% and 7.5% for pumps at 1240 nm, 762 nm and 425 nm, respectively. The DOP of PL caused by resonant excitation may be described in terms of a model of a partially anisotropic oscillator with the parameters represented by the principal axes of an ellipsoid. For the resonant excitation at 1240 nm, the ratio of the major principal axis to the minor one turned out to be 5.1 and 3.0 for BAC-P and BAC-Si, respectively.
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spelling doaj.art-1e5b290099944368853052e030a1515a2023-11-19T02:38:48ZengMDPI AGPhotonics2304-67322023-07-0110886010.3390/photonics10080860Polarized Luminescence of Bismuth Active Centers in Phosphosilicate GlassesAlexander V. Elopov0Konstantin E. Riumkin1Fedor V. Afanasiev2Sergey V. Alyshev3Alexander V. Kharakhordin4Aleksandr M. Khegai5Elena G. Firstova6Sergei V. Firstov7Konstantin N. Nishchev8Mikhail A. Melkumov9Dianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaG.G. Devyatykh Institute of Chemistry of High-Purity Substances of the Russian Academy of Sciences, 49 Tropinin Str., 603951 Nizhny Novgorod, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaInstitute of Science-Based Technologies and New Materials, National Research Ogarev Mordovia State University, 68 Bolshevistskaya Str., 430005 Saransk, RussiaDianov Fiber Optics Research Center, Prokhorov General Physics Institute of the Russian Academy of Sciences (GPI RAS), 38 Vavilov Str., 119333 Moscow, RussiaThe polarization properties of bismuth active centers (BACs) are important for many applications of bismuth-doped fibers, but they are still lacking in study. In this paper, we present the measurements of polarized luminescence (PL) of the BACs formed in a Bi-doped phosphosilicate glass matrix. This research was performed on phosphosilicate fiber preforms used for the drawing of active bismuth-doped fibers for efficient optical amplifiers and lasers. The degree of polarization (DOP) of luminescence of the BACs associated with phosphorus and silica (BAC-P and BAC-Si) is provided and discussed. The DOP of luminescence at the 1320 nm wavelength appeared to be around 19%, 0% and 7.5% for pumps at 1240 nm, 762 nm and 425 nm, respectively. The DOP of PL caused by resonant excitation may be described in terms of a model of a partially anisotropic oscillator with the parameters represented by the principal axes of an ellipsoid. For the resonant excitation at 1240 nm, the ratio of the major principal axis to the minor one turned out to be 5.1 and 3.0 for BAC-P and BAC-Si, respectively.https://www.mdpi.com/2304-6732/10/8/860bismuthfiberopticspolarization
spellingShingle Alexander V. Elopov
Konstantin E. Riumkin
Fedor V. Afanasiev
Sergey V. Alyshev
Alexander V. Kharakhordin
Aleksandr M. Khegai
Elena G. Firstova
Sergei V. Firstov
Konstantin N. Nishchev
Mikhail A. Melkumov
Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses
Photonics
bismuth
fiber
optics
polarization
title Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses
title_full Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses
title_fullStr Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses
title_full_unstemmed Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses
title_short Polarized Luminescence of Bismuth Active Centers in Phosphosilicate Glasses
title_sort polarized luminescence of bismuth active centers in phosphosilicate glasses
topic bismuth
fiber
optics
polarization
url https://www.mdpi.com/2304-6732/10/8/860
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