Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution

The batch removal of hexavalent chromium from aqueous solution by chitosan under different experimental conditions, such as the pH value and the initial hexavalent chromium ion concentration, was investigated. The adsorption of hexavalent chromium is highly pH-dependent, the results obtained in the...

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Main Authors: JinLong Yan, Guixiang Quan
Format: Article
Language:English
Published: SAGE Publishing 2009-11-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.27.9.835
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author JinLong Yan
Guixiang Quan
author_facet JinLong Yan
Guixiang Quan
author_sort JinLong Yan
collection DOAJ
description The batch removal of hexavalent chromium from aqueous solution by chitosan under different experimental conditions, such as the pH value and the initial hexavalent chromium ion concentration, was investigated. The adsorption of hexavalent chromium is highly pH-dependent, the results obtained in the present study indicating that the optimum pH for Cr(VI) ion removal was 4.0. The kinetics of the adsorption of Cr(VI) ions by chitosan were evaluated by the pseudo-first-order, pseudo-second-order, Elovich and intra-particle diffusion kinetic models, respectively. The results show that the pseudo-second-order kinetic model gave a good correlation (r 2 = 0.9942) with the experimental data.
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spelling doaj.art-1e5cb5c7039346d1ac4ce8b7cd9b5f0d2025-01-02T22:39:31ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382009-11-012710.1260/0263-6174.27.9.835Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous SolutionJinLong YanGuixiang QuanThe batch removal of hexavalent chromium from aqueous solution by chitosan under different experimental conditions, such as the pH value and the initial hexavalent chromium ion concentration, was investigated. The adsorption of hexavalent chromium is highly pH-dependent, the results obtained in the present study indicating that the optimum pH for Cr(VI) ion removal was 4.0. The kinetics of the adsorption of Cr(VI) ions by chitosan were evaluated by the pseudo-first-order, pseudo-second-order, Elovich and intra-particle diffusion kinetic models, respectively. The results show that the pseudo-second-order kinetic model gave a good correlation (r 2 = 0.9942) with the experimental data.https://doi.org/10.1260/0263-6174.27.9.835
spellingShingle JinLong Yan
Guixiang Quan
Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution
Adsorption Science & Technology
title Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution
title_full Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution
title_fullStr Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution
title_full_unstemmed Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution
title_short Kinetic Models of the Adsorption of Hexavalent Chromium by Chitosan from Aqueous Solution
title_sort kinetic models of the adsorption of hexavalent chromium by chitosan from aqueous solution
url https://doi.org/10.1260/0263-6174.27.9.835
work_keys_str_mv AT jinlongyan kineticmodelsoftheadsorptionofhexavalentchromiumbychitosanfromaqueoussolution
AT guixiangquan kineticmodelsoftheadsorptionofhexavalentchromiumbychitosanfromaqueoussolution