A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy
Under cooling rates of 2 ℃/s and 10 ℃/s, the influences of B content on the microstructure of near eutectic Al-13.0wt%Si alloy have been investigated. Results showed that the addition of boron resulted in refi nement of eutectic grains, and to some extent, had an inhibiting effect on precipitation o...
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| Format: | Article |
| Language: | English |
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Foundry Journal Agency
2008-05-01
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| Series: | China Foundry |
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| Online Access: | http://www.foundryworld.com/uploadfile/2008111450239609.pdf |
| _version_ | 1811265785517047808 |
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| author | Xi Xiao Zhou Jianyuan Lü Jianhua |
| author_facet | Xi Xiao Zhou Jianyuan Lü Jianhua |
| author_sort | Xi Xiao |
| collection | DOAJ |
| description | Under cooling rates of 2 ℃/s and 10 ℃/s, the influences of B content on the microstructure of near eutectic Al-13.0wt%Si alloy have been investigated. Results showed that the addition of boron resulted in refi nement of eutectic grains, and to some extent, had an inhibiting effect on precipitation of the primary phases, and the refi ning and inhibiting effects are much more obvious at higher cooling rate. When B was not added, higher cooling rate promoted the a-Al dendrites formation. At lower cooling rate, the addition of B did not cause the so called "columnar to equiaxed transition (CET)", however, at higher cooling rate, this transition was obvious. After the addition of B, the nucleation temperature TN ascended and nucleation mode changed from nucleation mode of from wall towards centre (without B addition) to a nucleation mode that the eutectic nucleated evenly throughout whole sample (with B added). It can be concluded that the addition of B offers a large amount of nuclei for eutectic solidifi cation, as a result, the eutectic grains was refi ned. Higher cooling rate will lead to more nuclei, so the effects on the refi nement of eutectic grains and on suppression of primary phases are increased. |
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| id | doaj.art-1e67ee6c3d2247f681ddbdfa44e1806b |
| institution | Directory Open Access Journal |
| issn | 1672-6421 |
| language | English |
| last_indexed | 2024-04-12T20:30:12Z |
| publishDate | 2008-05-01 |
| publisher | Foundry Journal Agency |
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| series | China Foundry |
| spelling | doaj.art-1e67ee6c3d2247f681ddbdfa44e1806b2022-12-22T03:17:45ZengFoundry Journal AgencyChina Foundry1672-64212008-05-0152119123A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloyXi XiaoZhou JianyuanLü JianhuaUnder cooling rates of 2 ℃/s and 10 ℃/s, the influences of B content on the microstructure of near eutectic Al-13.0wt%Si alloy have been investigated. Results showed that the addition of boron resulted in refi nement of eutectic grains, and to some extent, had an inhibiting effect on precipitation of the primary phases, and the refi ning and inhibiting effects are much more obvious at higher cooling rate. When B was not added, higher cooling rate promoted the a-Al dendrites formation. At lower cooling rate, the addition of B did not cause the so called "columnar to equiaxed transition (CET)", however, at higher cooling rate, this transition was obvious. After the addition of B, the nucleation temperature TN ascended and nucleation mode changed from nucleation mode of from wall towards centre (without B addition) to a nucleation mode that the eutectic nucleated evenly throughout whole sample (with B added). It can be concluded that the addition of B offers a large amount of nuclei for eutectic solidifi cation, as a result, the eutectic grains was refi ned. Higher cooling rate will lead to more nuclei, so the effects on the refi nement of eutectic grains and on suppression of primary phases are increased.http://www.foundryworld.com/uploadfile/2008111450239609.pdfAl-Si alloymicrostructurenucleationcooling rate |
| spellingShingle | Xi Xiao Zhou Jianyuan Lü Jianhua A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy China Foundry Al-Si alloy microstructure nucleation cooling rate |
| title | A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy |
| title_full | A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy |
| title_fullStr | A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy |
| title_full_unstemmed | A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy |
| title_short | A new thermodynamic expression for Gibbs free energy difference ΔG between the under-cooled liquid and on microstructure of near-eutectic Al-13wt%Si alloy |
| title_sort | new thermodynamic expression for gibbs free energy difference δg between the under cooled liquid and on microstructure of near eutectic al 13wt si alloy |
| topic | Al-Si alloy microstructure nucleation cooling rate |
| url | http://www.foundryworld.com/uploadfile/2008111450239609.pdf |
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