Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent

Adsorption is one of the most easy-to-operate, less costly, efficient and, most importantly, environmentally friendly methods of removing toxic metals from aqueous environments. We used spent Impra Green Tea Ginseng Flavoured to recover mercury (Hg2+), lead (Pb2+) and cadmium (Cd2+) in binary and t...

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Main Authors: Raphael B.H. Gameli, Elliot H. Alhassan, Abudu B. Duwiejuah, Emmanuel D. Abarike, Abdul-Aziz Bawa
Format: Article
Language:English
Published: Academy of Science of South Africa 2023-08-01
Series:South African Journal of Science
Subjects:
Online Access:https://sajs.co.za/article/view/13352
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author Raphael B.H. Gameli
Elliot H. Alhassan
Abudu B. Duwiejuah
Emmanuel D. Abarike
Abdul-Aziz Bawa
author_facet Raphael B.H. Gameli
Elliot H. Alhassan
Abudu B. Duwiejuah
Emmanuel D. Abarike
Abdul-Aziz Bawa
author_sort Raphael B.H. Gameli
collection DOAJ
description Adsorption is one of the most easy-to-operate, less costly, efficient and, most importantly, environmentally friendly methods of removing toxic metals from aqueous environments. We used spent Impra Green Tea Ginseng Flavoured to recover mercury (Hg2+), lead (Pb2+) and cadmium (Cd2+) in binary and ternary systems from greywater. We undertook this study in binary and ternary systems at adsorbent dosages with a corresponding 100 mL varied initial metal concentrations of the greywater. The adsorption efficiency at varied concentrations and dosages in the binary systems by the spent tea waste ranged from 38.5% to 100% for lead, 11.50% to 100% for cadmium and was 100% for mercury. In the ternary system, the adsorption efficiency of toxic metals ranged from 28.91% to 72.85% for cadmium and was 100% for mercury and lead. The maximum adsorption capacity (Qe) for toxic metals in the binary system ranged from 38.46 to 81.97 mg/g for Pb2+ and 12.64 to 56.82 mg/g for Cd2+. The Langmuir adsorption isotherm model was the best fit for the adsorption of toxic metals by Impra Green Tea Ginseng Flavoured. The pH under which the experiments were conducted showed very high removal efficiency for lead and mercury but lower removal efficiencies for cadmium. Spent Impra Green Tea Ginseng Flavoured can be used as an effective and low-cost adsorbent of toxic metals from greywater or wastewater. Based on our findings, further studies should be conducted to determine the effects of varying the contact time, temperature and elevated metal concentrations in the greywater or other wastewater. Significance: • This study provides useful information on how spent Impra Green Tea Ginseng Flavoured can be used as an effective and low-cost adsorbent of toxic metals from greywater or wastewater.
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spelling doaj.art-1e6a01ab30554bbd839ae6b4a84e93bb2023-08-09T06:38:00ZengAcademy of Science of South AfricaSouth African Journal of Science1996-74892023-08-011197/810.17159/sajs.2023/13352Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbentRaphael B.H. Gameli0Elliot H. Alhassan1Abudu B. Duwiejuah2Emmanuel D. Abarike3Abdul-Aziz Bawa4Department of Environment and Sustainability Sciences, Faculty of Natural Resources and Environment, University for Development Studies, Nyankpala Campus, Tamale, GhanaDepartment of Fisheries and Aquatic Resources Management, Faculty of Biosciences, University for Development Studies, Nyankpala Campus, Nyankpala, GhanaDepartment of Biotechnology and Molecular Biology, Faculty of Biosciences, University for Development Studies, Nyankpala Campus, Tamale, GhanaDepartment of Fisheries and Aquatic Resources Management, Faculty of Biosciences, University for Development Studies, Nyankpala Campus, Tamale, GhanaSpanish Laboratory Complex, University for Development Studies, Nyankpala Campus,Tamale, Ghana Adsorption is one of the most easy-to-operate, less costly, efficient and, most importantly, environmentally friendly methods of removing toxic metals from aqueous environments. We used spent Impra Green Tea Ginseng Flavoured to recover mercury (Hg2+), lead (Pb2+) and cadmium (Cd2+) in binary and ternary systems from greywater. We undertook this study in binary and ternary systems at adsorbent dosages with a corresponding 100 mL varied initial metal concentrations of the greywater. The adsorption efficiency at varied concentrations and dosages in the binary systems by the spent tea waste ranged from 38.5% to 100% for lead, 11.50% to 100% for cadmium and was 100% for mercury. In the ternary system, the adsorption efficiency of toxic metals ranged from 28.91% to 72.85% for cadmium and was 100% for mercury and lead. The maximum adsorption capacity (Qe) for toxic metals in the binary system ranged from 38.46 to 81.97 mg/g for Pb2+ and 12.64 to 56.82 mg/g for Cd2+. The Langmuir adsorption isotherm model was the best fit for the adsorption of toxic metals by Impra Green Tea Ginseng Flavoured. The pH under which the experiments were conducted showed very high removal efficiency for lead and mercury but lower removal efficiencies for cadmium. Spent Impra Green Tea Ginseng Flavoured can be used as an effective and low-cost adsorbent of toxic metals from greywater or wastewater. Based on our findings, further studies should be conducted to determine the effects of varying the contact time, temperature and elevated metal concentrations in the greywater or other wastewater. Significance: • This study provides useful information on how spent Impra Green Tea Ginseng Flavoured can be used as an effective and low-cost adsorbent of toxic metals from greywater or wastewater. https://sajs.co.za/article/view/13352adsorptionbinary systemgreywatermercurygreen tea
spellingShingle Raphael B.H. Gameli
Elliot H. Alhassan
Abudu B. Duwiejuah
Emmanuel D. Abarike
Abdul-Aziz Bawa
Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
South African Journal of Science
adsorption
binary system
greywater
mercury
green tea
title Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
title_full Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
title_fullStr Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
title_full_unstemmed Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
title_short Binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
title_sort binary and ternary metals adsorption from greywater using spent green tea as a novel adsorbent
topic adsorption
binary system
greywater
mercury
green tea
url https://sajs.co.za/article/view/13352
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