(2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
The Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)&am...
Main Authors: | , , |
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Format: | Article |
Language: | English |
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International Union of Crystallography
2009-07-01
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Series: | Acta Crystallographica Section E |
Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809020339 |
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author | Chui Lian Tan Kong Mun Lo Seik Weng Ng |
author_facet | Chui Lian Tan Kong Mun Lo Seik Weng Ng |
author_sort | Chui Lian Tan |
collection | DOAJ |
description | The Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—Hpyridinium...O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell. |
first_indexed | 2024-12-18T15:18:09Z |
format | Article |
id | doaj.art-1e8793431f8049bcafbd256b8bb20ef4 |
institution | Directory Open Access Journal |
issn | 1600-5368 |
language | English |
last_indexed | 2024-12-18T15:18:09Z |
publishDate | 2009-07-01 |
publisher | International Union of Crystallography |
record_format | Article |
series | Acta Crystallographica Section E |
spelling | doaj.art-1e8793431f8049bcafbd256b8bb20ef42022-12-21T21:03:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m721m72110.1107/S1600536809020339(2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)Chui Lian TanKong Mun LoSeik Weng NgThe Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—Hpyridinium...O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell.http://scripts.iucr.org/cgi-bin/paper?S1600536809020339 |
spellingShingle | Chui Lian Tan Kong Mun Lo Seik Weng Ng (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV) Acta Crystallographica Section E |
title | (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV) |
title_full | (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV) |
title_fullStr | (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV) |
title_full_unstemmed | (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV) |
title_short | (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV) |
title_sort | 2 amido 3 oxidopyridinium amp 954 2n o dibenzylchloridotin iv |
url | http://scripts.iucr.org/cgi-bin/paper?S1600536809020339 |
work_keys_str_mv | AT chuiliantan 2amido3oxidopyridiniumamp9542nodibenzylchloridotiniv AT kongmunlo 2amido3oxidopyridiniumamp9542nodibenzylchloridotiniv AT seikwengng 2amido3oxidopyridiniumamp9542nodibenzylchloridotiniv |