(2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)

The Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)&am...

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Main Authors: Chui Lian Tan, Kong Mun Lo, Seik Weng Ng
Format: Article
Language:English
Published: International Union of Crystallography 2009-07-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536809020339
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author Chui Lian Tan
Kong Mun Lo
Seik Weng Ng
author_facet Chui Lian Tan
Kong Mun Lo
Seik Weng Ng
author_sort Chui Lian Tan
collection DOAJ
description The Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—Hpyridinium...O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell.
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spelling doaj.art-1e8793431f8049bcafbd256b8bb20ef42022-12-21T21:03:28ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657m721m72110.1107/S1600536809020339(2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)Chui Lian TanKong Mun LoSeik Weng NgThe Sn atom in the title compound, [Sn(C7H7)2(C5H5N2O)Cl], shows a distorted C2ClNOSn trigonal-bipyramidal coordination, with a Cl–Sn–O axial angle of 163.77 (3)°, but the C—Sn—C angle [141.43 (7)°] deviates from 120°. The chelating ligand exists in a zwitterionic form. Adjacent molecules are linked by an N—Hpyridinium...O hydrogen bond, forming a chain running along the c axis of the orthorhombic unit cell.http://scripts.iucr.org/cgi-bin/paper?S1600536809020339
spellingShingle Chui Lian Tan
Kong Mun Lo
Seik Weng Ng
(2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
Acta Crystallographica Section E
title (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
title_full (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
title_fullStr (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
title_full_unstemmed (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
title_short (2-Amido-3-oxidopyridinium-κ2N,O)dibenzylchloridotin(IV)
title_sort 2 amido 3 oxidopyridinium amp 954 2n o dibenzylchloridotin iv
url http://scripts.iucr.org/cgi-bin/paper?S1600536809020339
work_keys_str_mv AT chuiliantan 2amido3oxidopyridiniumamp9542nodibenzylchloridotiniv
AT kongmunlo 2amido3oxidopyridiniumamp9542nodibenzylchloridotiniv
AT seikwengng 2amido3oxidopyridiniumamp9542nodibenzylchloridotiniv