Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time

The availability of clean water for drinking and domestic use is a basic human right, but it is oftentimes denied to some users due to lack of facilities that could clean water. The use of cheap and abundant biomaterials can help solve this problem. Spent coffee grounds is a biomaterial that can rem...

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Main Authors: Bandao-Antonio Jennifer, Malapit Giovanni, Mendoza John Paul, Valdez Joerandel
Format: Article
Language:English
Published: EDP Sciences 2022-01-01
Series:E3S Web of Conferences
Subjects:
Online Access:https://www.e3s-conferences.org/articles/e3sconf/pdf/2022/22/e3sconf_ri2c2022_02001.pdf
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author Bandao-Antonio Jennifer
Malapit Giovanni
Mendoza John Paul
Valdez Joerandel
author_facet Bandao-Antonio Jennifer
Malapit Giovanni
Mendoza John Paul
Valdez Joerandel
author_sort Bandao-Antonio Jennifer
collection DOAJ
description The availability of clean water for drinking and domestic use is a basic human right, but it is oftentimes denied to some users due to lack of facilities that could clean water. The use of cheap and abundant biomaterials can help solve this problem. Spent coffee grounds is a biomaterial that can remove heavy metals, such as lead (Pb2+) in water. In this study, the Ultraviolet Visible Spectrophotometry analysis resulted in the computation of the Total Removal Efficiency (R%) on lead (Pb2+) in water using raw, crushed, carbonized, and chemically treated spent coffee grounds of the Arabica variety. The crushed and carbonized samples had the highest Total Removal Efficiency (R%) at a shorter coffee-lead contact time. This is due to the exposure of more surfaces as seen in the Scanning Electron Microscopy micrographs, where more open pores and deeper cages or crevices are exposed for metal adsorption. The Atomic % of elemental Carbon was also high for the crushed sample. FTIR analysis revealed that the presence of charged amines (C=NH+) in the carbonized and chemically treated samples resulted to lead (Pb2+) adsorption in a short time. Abundant and cheap waste biomaterials, such as spent Arabica coffee grounds can exceed the Total Removal Efficiency (R%) on lead (Pb2+) of commercially available activated carbon.
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spelling doaj.art-1ea4f5710e7343af8646e3e1fd7d03442022-12-22T02:52:25ZengEDP SciencesE3S Web of Conferences2267-12422022-01-013550200110.1051/e3sconf/202235502001e3sconf_ri2c2022_02001Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact timeBandao-Antonio Jennifer0Malapit Giovanni1Mendoza John Paul2Valdez Joerandel3Department of Physical Sciences, University of the Philippines BaguioDepartment of Physical Sciences, University of the Philippines BaguioDepartment of Physical Sciences, University of the Philippines BaguioDepartment of Physical Sciences, University of the Philippines BaguioThe availability of clean water for drinking and domestic use is a basic human right, but it is oftentimes denied to some users due to lack of facilities that could clean water. The use of cheap and abundant biomaterials can help solve this problem. Spent coffee grounds is a biomaterial that can remove heavy metals, such as lead (Pb2+) in water. In this study, the Ultraviolet Visible Spectrophotometry analysis resulted in the computation of the Total Removal Efficiency (R%) on lead (Pb2+) in water using raw, crushed, carbonized, and chemically treated spent coffee grounds of the Arabica variety. The crushed and carbonized samples had the highest Total Removal Efficiency (R%) at a shorter coffee-lead contact time. This is due to the exposure of more surfaces as seen in the Scanning Electron Microscopy micrographs, where more open pores and deeper cages or crevices are exposed for metal adsorption. The Atomic % of elemental Carbon was also high for the crushed sample. FTIR analysis revealed that the presence of charged amines (C=NH+) in the carbonized and chemically treated samples resulted to lead (Pb2+) adsorption in a short time. Abundant and cheap waste biomaterials, such as spent Arabica coffee grounds can exceed the Total Removal Efficiency (R%) on lead (Pb2+) of commercially available activated carbon.https://www.e3s-conferences.org/articles/e3sconf/pdf/2022/22/e3sconf_ri2c2022_02001.pdfbiomaterialsspent coffee groundsheavy metalsadsorption
spellingShingle Bandao-Antonio Jennifer
Malapit Giovanni
Mendoza John Paul
Valdez Joerandel
Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time
E3S Web of Conferences
biomaterials
spent coffee grounds
heavy metals
adsorption
title Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time
title_full Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time
title_fullStr Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time
title_full_unstemmed Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time
title_short Lead (Pb2+) removal in water using different forms of spent arabica coffee grounds at varying contact time
title_sort lead pb2 removal in water using different forms of spent arabica coffee grounds at varying contact time
topic biomaterials
spent coffee grounds
heavy metals
adsorption
url https://www.e3s-conferences.org/articles/e3sconf/pdf/2022/22/e3sconf_ri2c2022_02001.pdf
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AT mendozajohnpaul leadpb2removalinwaterusingdifferentformsofspentarabicacoffeegroundsatvaryingcontacttime
AT valdezjoerandel leadpb2removalinwaterusingdifferentformsofspentarabicacoffeegroundsatvaryingcontacttime