Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
The development of highly effective Earth-abundant catalysts for C(sp2)-N cross-coupling represents an on-going challenge in synthetic chemistry. Here, the authors report a nickel complex containing a bisphosphine ancillary ligand allowing room-temperature couplings of amines and ammonia with a rang...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2016-03-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms11073 |
| _version_ | 1819194996652244992 |
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| author | Christopher M. Lavoie Preston M. MacQueen Nicolas L. Rotta-Loria Ryan S. Sawatzky Andrey Borzenko Alicia J. Chisholm Breanna K. V. Hargreaves Robert McDonald Michael J. Ferguson Mark Stradiotto |
| author_facet | Christopher M. Lavoie Preston M. MacQueen Nicolas L. Rotta-Loria Ryan S. Sawatzky Andrey Borzenko Alicia J. Chisholm Breanna K. V. Hargreaves Robert McDonald Michael J. Ferguson Mark Stradiotto |
| author_sort | Christopher M. Lavoie |
| collection | DOAJ |
| description | The development of highly effective Earth-abundant catalysts for C(sp2)-N cross-coupling represents an on-going challenge in synthetic chemistry. Here, the authors report a nickel complex containing a bisphosphine ancillary ligand allowing room-temperature couplings of amines and ammonia with a range of electrophiles. |
| first_indexed | 2024-12-23T02:05:44Z |
| format | Article |
| id | doaj.art-1ea983677eed44938be8c3fecf2ad18a |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-23T02:05:44Z |
| publishDate | 2016-03-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-1ea983677eed44938be8c3fecf2ad18a2022-12-21T18:03:52ZengNature PortfolioNature Communications2041-17232016-03-017111110.1038/ncomms11073Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand designChristopher M. Lavoie0Preston M. MacQueen1Nicolas L. Rotta-Loria2Ryan S. Sawatzky3Andrey Borzenko4Alicia J. Chisholm5Breanna K. V. Hargreaves6Robert McDonald7Michael J. Ferguson8Mark Stradiotto9Department of Chemistry, Dalhousie UniversityDepartment of Chemistry, Dalhousie UniversityDepartment of Chemistry, Dalhousie UniversityDepartment of Chemistry, Dalhousie UniversityDepartment of Chemistry, Dalhousie UniversityDepartment of Chemistry, Dalhousie UniversityDepartment of Chemistry, Dalhousie UniversityDepartment of Chemistry, X-Ray Crystallography Laboratory, University of AlbertaDepartment of Chemistry, X-Ray Crystallography Laboratory, University of AlbertaDepartment of Chemistry, Dalhousie UniversityThe development of highly effective Earth-abundant catalysts for C(sp2)-N cross-coupling represents an on-going challenge in synthetic chemistry. Here, the authors report a nickel complex containing a bisphosphine ancillary ligand allowing room-temperature couplings of amines and ammonia with a range of electrophiles.https://doi.org/10.1038/ncomms11073 |
| spellingShingle | Christopher M. Lavoie Preston M. MacQueen Nicolas L. Rotta-Loria Ryan S. Sawatzky Andrey Borzenko Alicia J. Chisholm Breanna K. V. Hargreaves Robert McDonald Michael J. Ferguson Mark Stradiotto Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design Nature Communications |
| title | Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design |
| title_full | Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design |
| title_fullStr | Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design |
| title_full_unstemmed | Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design |
| title_short | Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design |
| title_sort | challenging nickel catalysed amine arylations enabled by tailored ancillary ligand design |
| url | https://doi.org/10.1038/ncomms11073 |
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