Probing the Effect of Six-Membered N-Heterocyclic Carbene—6-Mes—on the Synthesis, Structure and Reactivity of Me2MOR(NHC) (M = Ga, In) Complexes

Probing the Effect of Six-Membered N-Heterocyclic Carbene—6-Mes—on the Synthesis, Structure and Reactivity of Me2MOR(NHC) (M = Ga, In) Complexes

The investigation of the reactivity of six membered N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)-3,4,5,6-tetrahydropyrimidin-1-ylidene (6-Mes) towards dialkylgallium and dialkylindium alkoxides/aryloxides has shown that both steric hindrances and donor properties of 6-Mes significantly infl...

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Bibliographic Details
Main Authors:	Martyna Cybularczyk-Cecotka, Anna Maria Dąbrowska, Piotr A. Guńka, Paweł Horeglad
Format:	Article
Language:	English
Published:	MDPI AG 2018-02-01
Series:	Inorganics
Subjects:	metal alkoxides main group metals NHC donor strength catalyst lactide stereoselectivity isotactic polylactide
Online Access:	http://www.mdpi.com/2304-6740/6/1/28

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