Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II)
The title structure, K2[Co(C11N4O3)2(H2O)4], is isotypic with K2[Fe(C11N4O3)2(H2O)4]. The CoII atom is in a distorted octahedral CoN2O4 geometry, forming a dianionic mononuclear entity. Each dianionic unit is associated with two potassium cations and interacts with adjacent units through O&#...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810048646 |
| _version_ | 1828884698387972096 |
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| author | Jan Janczak Flavia C. Machado Luiz Fernando C. de Oliveira Renata Diniz Luciano Honorato Chagas |
| author_facet | Jan Janczak Flavia C. Machado Luiz Fernando C. de Oliveira Renata Diniz Luciano Honorato Chagas |
| author_sort | Jan Janczak |
| collection | DOAJ |
| description | The title structure, K2[Co(C11N4O3)2(H2O)4], is isotypic with K2[Fe(C11N4O3)2(H2O)4]. The CoII atom is in a distorted octahedral CoN2O4 geometry, forming a dianionic mononuclear entity. Each dianionic unit is associated with two potassium cations and interacts with adjacent units through O—H...N and O—H...O hydrogen bonds. |
| first_indexed | 2024-12-13T11:12:59Z |
| format | Article |
| id | doaj.art-1ef1eff5e279462588e4ea5333194534 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T11:12:59Z |
| publishDate | 2010-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1ef1eff5e279462588e4ea53331945342022-12-21T23:48:42ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-12-016612m1673m167410.1107/S1600536810048646Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II)Jan JanczakFlavia C. MachadoLuiz Fernando C. de OliveiraRenata DinizLuciano Honorato ChagasThe title structure, K2[Co(C11N4O3)2(H2O)4], is isotypic with K2[Fe(C11N4O3)2(H2O)4]. The CoII atom is in a distorted octahedral CoN2O4 geometry, forming a dianionic mononuclear entity. Each dianionic unit is associated with two potassium cations and interacts with adjacent units through O—H...N and O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536810048646 |
| spellingShingle | Jan Janczak Flavia C. Machado Luiz Fernando C. de Oliveira Renata Diniz Luciano Honorato Chagas Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II) Acta Crystallographica Section E |
| title | Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II) |
| title_full | Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II) |
| title_fullStr | Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II) |
| title_full_unstemmed | Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II) |
| title_short | Dipotassium tetraaquabis[3,5-bis(dicyanomethylene)cyclopentane-1,2,4-trionato(1−)-κN]cobaltate(II) |
| title_sort | dipotassium tetraaquabis 3 5 bis dicyanomethylene cyclopentane 1 2 4 trionato 1 amp 8722 amp 954 n cobaltate ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810048646 |
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