Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate]
In the title compound, {[Cu(C12H10O8)(C12H8N2)]·H2O}n, the CuII ion is five-coordinated by two N atoms from one phenanthroline ligand and three O atoms from three different H2L2− anions (H4L is bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid) in a distorted square-pyramidal g...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
|
| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808037999 |
| _version_ | 1819291343389720576 |
|---|---|
| author | Ji-Cheng Ma Xing-Qi Li Yu-Jiang Zhuo Yun-Yu Liu |
| author_facet | Ji-Cheng Ma Xing-Qi Li Yu-Jiang Zhuo Yun-Yu Liu |
| author_sort | Ji-Cheng Ma |
| collection | DOAJ |
| description | In the title compound, {[Cu(C12H10O8)(C12H8N2)]·H2O}n, the CuII ion is five-coordinated by two N atoms from one phenanthroline ligand and three O atoms from three different H2L2− anions (H4L is bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid) in a distorted square-pyramidal geometry. Each H2L2− ion bridges three CuII atoms to form a zigzag sheet parallel to the ab plane. The crystal structure is consolidated by O—H...O hydrogen bonds. |
| first_indexed | 2024-12-24T03:37:08Z |
| format | Article |
| id | doaj.art-1ef61d7c147040dabf63d57504e40f27 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:37:08Z |
| publishDate | 2008-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1ef61d7c147040dabf63d57504e40f272022-12-21T17:17:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412m1590m159010.1107/S1600536808037999Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate]Ji-Cheng MaXing-Qi LiYu-Jiang ZhuoYun-Yu LiuIn the title compound, {[Cu(C12H10O8)(C12H8N2)]·H2O}n, the CuII ion is five-coordinated by two N atoms from one phenanthroline ligand and three O atoms from three different H2L2− anions (H4L is bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acid) in a distorted square-pyramidal geometry. Each H2L2− ion bridges three CuII atoms to form a zigzag sheet parallel to the ab plane. The crystal structure is consolidated by O—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808037999 |
| spellingShingle | Ji-Cheng Ma Xing-Qi Li Yu-Jiang Zhuo Yun-Yu Liu Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate] Acta Crystallographica Section E |
| title | Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate] |
| title_full | Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate] |
| title_fullStr | Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate] |
| title_full_unstemmed | Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate] |
| title_short | Poly[[(μ3-5,6-dicarboxybicyclo[2.2.2]oct-7-ene-2,3-dicarboxylato)(1,10-phenanthroline)copper(II)] monohydrate] |
| title_sort | poly 956 3 5 6 dicarboxybicyclo 2 2 2 oct 7 ene 2 3 dicarboxylato 1 10 phenanthroline copper ii monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808037999 |
| work_keys_str_mv | AT jichengma poly956356dicarboxybicyclo222oct7ene23dicarboxylato110phenanthrolinecopperiimonohydrate AT xingqili poly956356dicarboxybicyclo222oct7ene23dicarboxylato110phenanthrolinecopperiimonohydrate AT yujiangzhuo poly956356dicarboxybicyclo222oct7ene23dicarboxylato110phenanthrolinecopperiimonohydrate AT yunyuliu poly956356dicarboxybicyclo222oct7ene23dicarboxylato110phenanthrolinecopperiimonohydrate |