Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland

Man-made halocarbons have a considerable impact on the environment. Chlorine- and bromine-containing organic compounds such as chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are responsible for the decline of stratospheric ozone and their use has therefore been regulated i...

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Main Authors: Brigitte Buchmann, Konrad Stemmler, Stefan Reimann
Format: Article
Language:deu
Published: Swiss Chemical Society 2003-09-01
Series:CHIMIA
Subjects:
Online Access:https://chimia.ch/chimia/article/view/3733
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author Brigitte Buchmann
Konrad Stemmler
Stefan Reimann
author_facet Brigitte Buchmann
Konrad Stemmler
Stefan Reimann
author_sort Brigitte Buchmann
collection DOAJ
description Man-made halocarbons have a considerable impact on the environment. Chlorine- and bromine-containing organic compounds such as chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are responsible for the decline of stratospheric ozone and their use has therefore been regulated in the Montreal Protocol. Fluoro-containing halocarbons are not regulated within this treaty, but as all halocarbons act as greenhouse gases, this group of compounds was included in the Kyoto Protocol. Halogenated ozone destroying CFCs and chlorinated solvents were continuously measured in Switzerland at a suburban site near Zürich (Dübendorf) from 1994 until 2000 and since 2000 at the high alpine site of Jungfraujoch together with all greenhouse-active halocarbons. Furthermore, all anthropogenic halocarbons were measured in a campaign in Dübendorf in 2002. The analysis of the measurements confirms that a substantial decline of their emissions took place as a consequence of the Montreal Protocol. On the other hand, the concentration of substitutes such as hydrofluorocarbons (HFCs) increased dramatically. Linking continuously measured time series with meteorological information allows an estimation of regional emissions of the regulated compounds for Switzerland. In contrast to trade survey statistics or inventories, this method is an efficient tool to track the development of diffusive emissions of substances in long term usage such as foams and refrigerant systems.
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spelling doaj.art-1efc23b9ee6444d6977a28a0ef9556492022-12-22T04:36:05ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24242003-09-0157910.2533/000942903777678966Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in SwitzerlandBrigitte BuchmannKonrad StemmlerStefan Reimann Man-made halocarbons have a considerable impact on the environment. Chlorine- and bromine-containing organic compounds such as chlorofluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) are responsible for the decline of stratospheric ozone and their use has therefore been regulated in the Montreal Protocol. Fluoro-containing halocarbons are not regulated within this treaty, but as all halocarbons act as greenhouse gases, this group of compounds was included in the Kyoto Protocol. Halogenated ozone destroying CFCs and chlorinated solvents were continuously measured in Switzerland at a suburban site near Zürich (Dübendorf) from 1994 until 2000 and since 2000 at the high alpine site of Jungfraujoch together with all greenhouse-active halocarbons. Furthermore, all anthropogenic halocarbons were measured in a campaign in Dübendorf in 2002. The analysis of the measurements confirms that a substantial decline of their emissions took place as a consequence of the Montreal Protocol. On the other hand, the concentration of substitutes such as hydrofluorocarbons (HFCs) increased dramatically. Linking continuously measured time series with meteorological information allows an estimation of regional emissions of the regulated compounds for Switzerland. In contrast to trade survey statistics or inventories, this method is an efficient tool to track the development of diffusive emissions of substances in long term usage such as foams and refrigerant systems. https://chimia.ch/chimia/article/view/3733Atmospheric halocarbonsCfcEmission estimationGcmsMontreal protocol
spellingShingle Brigitte Buchmann
Konrad Stemmler
Stefan Reimann
Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland
CHIMIA
Atmospheric halocarbons
Cfc
Emission estimation
Gcms
Montreal protocol
title Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland
title_full Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland
title_fullStr Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland
title_full_unstemmed Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland
title_short Regional Emissions of Anthropogenic Halocarbons Derived from Continuous Measurements of Ambient Air in Switzerland
title_sort regional emissions of anthropogenic halocarbons derived from continuous measurements of ambient air in switzerland
topic Atmospheric halocarbons
Cfc
Emission estimation
Gcms
Montreal protocol
url https://chimia.ch/chimia/article/view/3733
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AT konradstemmler regionalemissionsofanthropogenichalocarbonsderivedfromcontinuousmeasurementsofambientairinswitzerland
AT stefanreimann regionalemissionsofanthropogenichalocarbonsderivedfromcontinuousmeasurementsofambientairinswitzerland