Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters

The purpose of this paper is the investigation of the capability of electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton for decolorization and degradation of synthetic aqueous solutions and actual dye house effluents containing nylanthrene red reactive dye. All...

Full description

Bibliographic Details
Main Authors: D. Marmanis, K. Dermentzis, A. Christoforidis
Format: Article
Language:English
Published: Eastern Macedonia and Thrace Institute of Technology 2016-04-01
Series:Journal of Engineering Science and Technology Review
Subjects:
Online Access:http://www.jestr.org/downloads/Volume9Issue1/fulltext91172016.pdf
_version_ 1818230367725813760
author D. Marmanis
K. Dermentzis
A. Christoforidis
author_facet D. Marmanis
K. Dermentzis
A. Christoforidis
author_sort D. Marmanis
collection DOAJ
description The purpose of this paper is the investigation of the capability of electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton for decolorization and degradation of synthetic aqueous solutions and actual dye house effluents containing nylanthrene red reactive dye. All electrochemical experiments with the synthetic dye solutions were conducted in electrochemical cell of volume 500 ml containing 200 mL of dye solution at concentration 50 mg/L and interelectrode distance of 1 cm. The three different electrochemical processes were analyzed, and their removal efficiencies were measured and evaluated. In addition, a flow diagram is designed for a continuously operated electrochemical process for remediation of synthetic and actual dye house effluents laden with nylanthrene dye. In the electrocoagulation process with aluminum electrodes, the colored aqueous dye solution was treated at the applied current densities of 5, 10 and 15 mA/cm2 and was quantitatively decolorized in 11, 9 and less than 6 minutes of electroprocessing time respectively. The electrooxidation process conducted with Ti/Pt and boron doped diamond (BDD) electrodes, at the applied current density of 10 mA/cm2 led to the quantitative decolorization and destruction of the dye in 25 and 15 min respectively. In the electro-Fenton process with iron electrodes, supply of added hydrogen peroxide and applied current density of 10 mA/cm2, complete decolorization and degradation of the nylanthrene red dye occurred in 6 min. The actual polyamide textile dyeing effluent of same volume 200 mL with initial turbidity of 114 NTU and COD of 1755 mg/L was treated by electrocoagulation at the same applied current density of 10 mA/cm2. The turbidity was quantitatively eliminated in only 10 min, while COD was reduced by 74.5 % in 40 minutes of electrolysis time.
first_indexed 2024-12-12T10:33:22Z
format Article
id doaj.art-1f112a0a44a84ba89a24b4f3c5d71619
institution Directory Open Access Journal
issn 1791-2377
1791-2377
language English
last_indexed 2024-12-12T10:33:22Z
publishDate 2016-04-01
publisher Eastern Macedonia and Thrace Institute of Technology
record_format Article
series Journal of Engineering Science and Technology Review
spelling doaj.art-1f112a0a44a84ba89a24b4f3c5d716192022-12-22T00:27:17ZengEastern Macedonia and Thrace Institute of TechnologyJournal of Engineering Science and Technology Review1791-23771791-23772016-04-0191111115Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing WastewatersD. Marmanis0 K. Dermentzis1A. Christoforidis2Laboratory of Environmental Protection, Department of Petroleum and Mechanical Engineering, Eastern / Hephaestus Advanced Research Laboratory, Eastern Macedonia and Thrace Institute of Technology, EMaTTech, 65404 Agios Loukas, Kavala, HellasLaboratory of General and Physical Chemistry, Department of Petroleum and Mechanical Engineering, Eastern Macedonia and Thrace Institute of Technology, EMaTTech, 65404 Agios Loukas, Kavala, Hellas / Hephaestus Advanced Research Laboratory, Eastern Macedonia and Thrace Institute of Technology, EMaTTech, 65404 Agios Loukas, Kavala, HellasLaboratory of Environmental Protection, Department of Petroleum and Mechanical Engineering, Eastern / Hephaestus Advanced Research Laboratory, Eastern Macedonia and Thrace Institute of Technology, EMaTTech, 65404 Agios Loukas, Kavala, HellasThe purpose of this paper is the investigation of the capability of electrochemical methods, such as electrocoagulation, electrooxidation and electro-Fenton for decolorization and degradation of synthetic aqueous solutions and actual dye house effluents containing nylanthrene red reactive dye. All electrochemical experiments with the synthetic dye solutions were conducted in electrochemical cell of volume 500 ml containing 200 mL of dye solution at concentration 50 mg/L and interelectrode distance of 1 cm. The three different electrochemical processes were analyzed, and their removal efficiencies were measured and evaluated. In addition, a flow diagram is designed for a continuously operated electrochemical process for remediation of synthetic and actual dye house effluents laden with nylanthrene dye. In the electrocoagulation process with aluminum electrodes, the colored aqueous dye solution was treated at the applied current densities of 5, 10 and 15 mA/cm2 and was quantitatively decolorized in 11, 9 and less than 6 minutes of electroprocessing time respectively. The electrooxidation process conducted with Ti/Pt and boron doped diamond (BDD) electrodes, at the applied current density of 10 mA/cm2 led to the quantitative decolorization and destruction of the dye in 25 and 15 min respectively. In the electro-Fenton process with iron electrodes, supply of added hydrogen peroxide and applied current density of 10 mA/cm2, complete decolorization and degradation of the nylanthrene red dye occurred in 6 min. The actual polyamide textile dyeing effluent of same volume 200 mL with initial turbidity of 114 NTU and COD of 1755 mg/L was treated by electrocoagulation at the same applied current density of 10 mA/cm2. The turbidity was quantitatively eliminated in only 10 min, while COD was reduced by 74.5 % in 40 minutes of electrolysis time.http://www.jestr.org/downloads/Volume9Issue1/fulltext91172016.pdfdye house effluentselectrochemical coagulationelectrooxidationelectro FentonBDD - Ti/Pt anodes.
spellingShingle D. Marmanis
K. Dermentzis
A. Christoforidis
Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters
Journal of Engineering Science and Technology Review
dye house effluents
electrochemical coagulation
electrooxidation
electro Fenton
BDD - Ti/Pt anodes.
title Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters
title_full Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters
title_fullStr Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters
title_full_unstemmed Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters
title_short Design and Application of Electrochemical Processes for Decolorization Treatment of Nylanthrene Red dye Bearing Wastewaters
title_sort design and application of electrochemical processes for decolorization treatment of nylanthrene red dye bearing wastewaters
topic dye house effluents
electrochemical coagulation
electrooxidation
electro Fenton
BDD - Ti/Pt anodes.
url http://www.jestr.org/downloads/Volume9Issue1/fulltext91172016.pdf
work_keys_str_mv AT dmarmanis designandapplicationofelectrochemicalprocessesfordecolorizationtreatmentofnylanthrenereddyebearingwastewaters
AT kdermentzis designandapplicationofelectrochemicalprocessesfordecolorizationtreatmentofnylanthrenereddyebearingwastewaters
AT achristoforidis designandapplicationofelectrochemicalprocessesfordecolorizationtreatmentofnylanthrenereddyebearingwastewaters