Transition phases of zeolite Faujasite type to Sodalite by thermal treatment

The zeolites can have several functions as catalysts (biofuel production) and molecular sieves (treatment of contaminated areas). This study aims to characterize the zeolites obtained in the transition of a Faujasite like zeolite into a Sodalite, when submitted to different thermal treatment times....

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Main Authors: Katia K. Kaminishikawahara, Laura J. Pereira, Éder C. F. de Souza, Maria Elena Payret Arrúa, Sandra Regina Masetto Antunes, André V. C. de Andrade, Helton J. Alves, Augusto C. Antunes
Format: Article
Language:English
Published: Universidade Estadual de Londrina 2015-10-01
Series:Semina: Ciências Exatas e Tecnológicas
Subjects:
Online Access:http://www.uel.br/revistas/uel/index.php/semexatas/article/view/20793/17142
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author Katia K. Kaminishikawahara
Laura J. Pereira
Éder C. F. de Souza
Maria Elena Payret Arrúa
Sandra Regina Masetto Antunes
André V. C. de Andrade
Helton J. Alves
Augusto C. Antunes
author_facet Katia K. Kaminishikawahara
Laura J. Pereira
Éder C. F. de Souza
Maria Elena Payret Arrúa
Sandra Regina Masetto Antunes
André V. C. de Andrade
Helton J. Alves
Augusto C. Antunes
author_sort Katia K. Kaminishikawahara
collection DOAJ
description The zeolites can have several functions as catalysts (biofuel production) and molecular sieves (treatment of contaminated areas). This study aims to characterize the zeolites obtained in the transition of a Faujasite like zeolite into a Sodalite, when submitted to different thermal treatment times. The synthesized zeolites were characterized by X-ray diffraction where the crystalline phases were identified: Faujasite, Sodalite, SiO2 and amorphous material. The 4 hours heat treatment produces zeolite crystal structure similar to Faujasite, having basic sites, surface area of 552.7 m2 g-1 , and pore volume of 0.3391 cm3 g-1. With increasing time of heat treatment was observed the transition to the Sodalite phase witch containing 0.277 mmol g-1 of basic active sites with surface area of 11.38 m2 g-1 and pore volume of 0.0651 cm3 g-1. By the Rietveld method was identified and quantified the presence of Sodalite and Hidrossodalite in samples with 24 and 30 hours of reaction times.
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spelling doaj.art-1f157f2f730241eeb309e832fc5ccc2c2022-12-22T02:40:05ZengUniversidade Estadual de LondrinaSemina: Ciências Exatas e Tecnológicas1676-54511679-03752015-10-01362718410.5433/1679-0375.2015v36n2p71Transition phases of zeolite Faujasite type to Sodalite by thermal treatmentKatia K. Kaminishikawahara0 Laura J. Pereira1Éder C. F. de Souza2Maria Elena Payret Arrúa3Sandra Regina Masetto Antunes4André V. C. de Andrade5Helton J. Alves6Augusto C. Antunes7UEPGUEPGUEPGUEPGUEPGUEPGUFPRUEPGThe zeolites can have several functions as catalysts (biofuel production) and molecular sieves (treatment of contaminated areas). This study aims to characterize the zeolites obtained in the transition of a Faujasite like zeolite into a Sodalite, when submitted to different thermal treatment times. The synthesized zeolites were characterized by X-ray diffraction where the crystalline phases were identified: Faujasite, Sodalite, SiO2 and amorphous material. The 4 hours heat treatment produces zeolite crystal structure similar to Faujasite, having basic sites, surface area of 552.7 m2 g-1 , and pore volume of 0.3391 cm3 g-1. With increasing time of heat treatment was observed the transition to the Sodalite phase witch containing 0.277 mmol g-1 of basic active sites with surface area of 11.38 m2 g-1 and pore volume of 0.0651 cm3 g-1. By the Rietveld method was identified and quantified the presence of Sodalite and Hidrossodalite in samples with 24 and 30 hours of reaction times.http://www.uel.br/revistas/uel/index.php/semexatas/article/view/20793/17142ZeolitesCatalystsMolecular SievesFaujasiteSodalite
spellingShingle Katia K. Kaminishikawahara
Laura J. Pereira
Éder C. F. de Souza
Maria Elena Payret Arrúa
Sandra Regina Masetto Antunes
André V. C. de Andrade
Helton J. Alves
Augusto C. Antunes
Transition phases of zeolite Faujasite type to Sodalite by thermal treatment
Semina: Ciências Exatas e Tecnológicas
Zeolites
Catalysts
Molecular Sieves
Faujasite
Sodalite
title Transition phases of zeolite Faujasite type to Sodalite by thermal treatment
title_full Transition phases of zeolite Faujasite type to Sodalite by thermal treatment
title_fullStr Transition phases of zeolite Faujasite type to Sodalite by thermal treatment
title_full_unstemmed Transition phases of zeolite Faujasite type to Sodalite by thermal treatment
title_short Transition phases of zeolite Faujasite type to Sodalite by thermal treatment
title_sort transition phases of zeolite faujasite type to sodalite by thermal treatment
topic Zeolites
Catalysts
Molecular Sieves
Faujasite
Sodalite
url http://www.uel.br/revistas/uel/index.php/semexatas/article/view/20793/17142
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