Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives
The breakthrough in Ln(III)-based SMMs with Schiff base ligands have been occurred for the last decade on account of their magnetic behavior, anisotropy and relaxation pathways. Herein, we review the synthetic strategy, from a structural point of view and magnetic properties of mono, di, tri and pol...
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| Format: | Article |
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MDPI AG
2020-12-01
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| Series: | Inorganics |
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| Online Access: | https://www.mdpi.com/2304-6740/8/12/66 |
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| author | Mamo Gebrezgiabher Yosef Bayeh Tesfay Gebretsadik Gebrehiwot Gebreslassie Fikre Elemo Madhu Thomas Wolfgang Linert |
| author_facet | Mamo Gebrezgiabher Yosef Bayeh Tesfay Gebretsadik Gebrehiwot Gebreslassie Fikre Elemo Madhu Thomas Wolfgang Linert |
| author_sort | Mamo Gebrezgiabher |
| collection | DOAJ |
| description | The breakthrough in Ln(III)-based SMMs with Schiff base ligands have been occurred for the last decade on account of their magnetic behavior, anisotropy and relaxation pathways. Herein, we review the synthetic strategy, from a structural point of view and magnetic properties of mono, di, tri and polynuclear Ln(III)-based single-molecule magnets mainly with Schiff bases of Salicylaldehyde origin. Special attention has been given to some important breakthroughs that are changing the perspective of this field with a special emphasis on slow magnetic relaxation. An overview of 50 Ln(III)-Schiff base complexes with SMM behavior, covering the period 2008–2020, which have been critical in understanding the magnetic interactions between the Ln(III)-centers, are presented and discussed in detail. |
| first_indexed | 2024-03-10T14:19:11Z |
| format | Article |
| id | doaj.art-1f20f8e5739d4db9a78485448c04b987 |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-10T14:19:11Z |
| publishDate | 2020-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-1f20f8e5739d4db9a78485448c04b9872023-11-20T23:31:16ZengMDPI AGInorganics2304-67402020-12-018126610.3390/inorganics8120066Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde DerivativesMamo Gebrezgiabher0Yosef Bayeh1Tesfay Gebretsadik2Gebrehiwot Gebreslassie3Fikre Elemo4Madhu Thomas5Wolfgang Linert6Department of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, EthiopiaDepartment of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, EthiopiaDepartment of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, EthiopiaDepartment of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, EthiopiaDepartment of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, EthiopiaDepartment of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University, Addis Ababa P.O. Box 16417, EthiopiaInstitute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-AC, 1060 Vienna, AustriaThe breakthrough in Ln(III)-based SMMs with Schiff base ligands have been occurred for the last decade on account of their magnetic behavior, anisotropy and relaxation pathways. Herein, we review the synthetic strategy, from a structural point of view and magnetic properties of mono, di, tri and polynuclear Ln(III)-based single-molecule magnets mainly with Schiff bases of Salicylaldehyde origin. Special attention has been given to some important breakthroughs that are changing the perspective of this field with a special emphasis on slow magnetic relaxation. An overview of 50 Ln(III)-Schiff base complexes with SMM behavior, covering the period 2008–2020, which have been critical in understanding the magnetic interactions between the Ln(III)-centers, are presented and discussed in detail.https://www.mdpi.com/2304-6740/8/12/66lanthanidesSchiff basesynthetic strategiessingle-molecule magnets |
| spellingShingle | Mamo Gebrezgiabher Yosef Bayeh Tesfay Gebretsadik Gebrehiwot Gebreslassie Fikre Elemo Madhu Thomas Wolfgang Linert Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives Inorganics lanthanides Schiff base synthetic strategies single-molecule magnets |
| title | Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives |
| title_full | Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives |
| title_fullStr | Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives |
| title_full_unstemmed | Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives |
| title_short | Lanthanide-Based Single-Molecule Magnets Derived from Schiff Base Ligands of Salicylaldehyde Derivatives |
| title_sort | lanthanide based single molecule magnets derived from schiff base ligands of salicylaldehyde derivatives |
| topic | lanthanides Schiff base synthetic strategies single-molecule magnets |
| url | https://www.mdpi.com/2304-6740/8/12/66 |
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