[4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate
In the title complex, [Cu(C20H13BrN4)(C18H15P)2]BF4·0.5CH2Cl2, the copper(I) cation adopts a distorted tetrahedral arrangement, coordinated by two triphenylphosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-molecule of dichloromethane crystallizes w...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807066238 |
| _version_ | 1818914617848496128 |
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| author | Matthew I. J. Polson Garry S. Hanan Nicholas J. Taylor |
| author_facet | Matthew I. J. Polson Garry S. Hanan Nicholas J. Taylor |
| author_sort | Matthew I. J. Polson |
| collection | DOAJ |
| description | In the title complex, [Cu(C20H13BrN4)(C18H15P)2]BF4·0.5CH2Cl2, the copper(I) cation adopts a distorted tetrahedral arrangement, coordinated by two triphenylphosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-molecule of dichloromethane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine interacts weakly with the copper centre at a distance of 3.071 Å. |
| first_indexed | 2024-12-19T23:49:14Z |
| format | Article |
| id | doaj.art-1f2e50514ad14050a0c9d70a72ca2921 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:49:14Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1f2e50514ad14050a0c9d70a72ca29212022-12-21T20:01:12ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m205m20510.1107/S1600536807066238[4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvateMatthew I. J. PolsonGarry S. HananNicholas J. TaylorIn the title complex, [Cu(C20H13BrN4)(C18H15P)2]BF4·0.5CH2Cl2, the copper(I) cation adopts a distorted tetrahedral arrangement, coordinated by two triphenylphosphine ligands and two N atoms of the potentially tridentate terpyridine ligand. One half-molecule of dichloromethane crystallizes with the complex. The chlorine atoms are disordered over two sites with occupancies fixed at 0.30 and 0.20 respectively. The N donor atom of the central pyridine interacts weakly with the copper centre at a distance of 3.071 Å.http://scripts.iucr.org/cgi-bin/paper?S1600536807066238 |
| spellingShingle | Matthew I. J. Polson Garry S. Hanan Nicholas J. Taylor [4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate Acta Crystallographica Section E |
| title | [4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate |
| title_full | [4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate |
| title_fullStr | [4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate |
| title_full_unstemmed | [4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate |
| title_short | [4′-(2-Bromo-5-pyridyl)-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′]bis(triphenylphosphine-κP)copper(I) tetrafluoridoborate dichloromethane hemisolvate |
| title_sort | 4 8242 2 bromo 5 pyridyl 2 2 8242 6 8242 2 8242 8242 terpyridine 954 3n n 8242 n 8242 8242 bis triphenylphosphine 954 p copper i tetrafluoridoborate dichloromethane hemisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807066238 |
| work_keys_str_mv | AT matthewijpolson 482422bromo5pyridyl22824268242282428242terpyridine9543nn8242n82428242bistriphenylphosphine954pcopperitetrafluoridoboratedichloromethanehemisolvate AT garryshanan 482422bromo5pyridyl22824268242282428242terpyridine9543nn8242n82428242bistriphenylphosphine954pcopperitetrafluoridoboratedichloromethanehemisolvate AT nicholasjtaylor 482422bromo5pyridyl22824268242282428242terpyridine9543nn8242n82428242bistriphenylphosphine954pcopperitetrafluoridoboratedichloromethanehemisolvate |