Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II)
In the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd—N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex c...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-01-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536807066627 |
| _version_ | 1818974038603595776 |
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| author | Simphiwe M. Nelana Gert J. Kruger James Darkwa |
| author_facet | Simphiwe M. Nelana Gert J. Kruger James Darkwa |
| author_sort | Simphiwe M. Nelana |
| collection | DOAJ |
| description | In the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd—N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N—H...Cl linkages. |
| first_indexed | 2024-12-20T15:33:42Z |
| format | Article |
| id | doaj.art-1f47fed6206f4ff2abee49c54c6d902c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T15:33:42Z |
| publishDate | 2008-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1f47fed6206f4ff2abee49c54c6d902c2022-12-21T19:35:31ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-01-01641m206m20710.1107/S1600536807066627Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II)Simphiwe M. NelanaGert J. KrugerJames DarkwaIn the title compound, [PdCl2(C5H8N2)(C12H12N2O)], the Pd atom adopts a slightly distorted trans-PdCl2N2 square-planar arrangement. The different Pd—N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N—H...Cl linkages.http://scripts.iucr.org/cgi-bin/paper?S1600536807066627 |
| spellingShingle | Simphiwe M. Nelana Gert J. Kruger James Darkwa Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II) Acta Crystallographica Section E |
| title | Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II) |
| title_full | Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II) |
| title_fullStr | Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II) |
| title_full_unstemmed | Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II) |
| title_short | Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tolyl)methanone]palladium(II) |
| title_sort | dichlorido 3 5 dimethyl 1h pyrazole 3 5 dimethyl 1h pyrazol 1 yl o tolyl methanone palladium ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536807066627 |
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