Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions

In this paper, TiO2 nanotubes are fabricated on Ti foils by anodic oxidation, a layer of ZnO nanorod arrays is further deposited on the TiO2 nanotube without seed layer by a hydrothermal method at different Zn2+ concentration. The result shows that the ZnO nanorods mainly present needle-like structu...

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Main Authors: Fang Wang, Dengji Yu, Jun Dai
Format: Article
Language:English
Published: AIP Publishing LLC 2019-03-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.5090306
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author Fang Wang
Dengji Yu
Jun Dai
author_facet Fang Wang
Dengji Yu
Jun Dai
author_sort Fang Wang
collection DOAJ
description In this paper, TiO2 nanotubes are fabricated on Ti foils by anodic oxidation, a layer of ZnO nanorod arrays is further deposited on the TiO2 nanotube without seed layer by a hydrothermal method at different Zn2+ concentration. The result shows that the ZnO nanorods mainly present needle-like structure and the density of the nanorods increases with the Zn2+ concentration. The PL of the ZnO nanorods show that there are defect levels formed in the ZnO nanorods. When the ZnO/TiO2 heterostructure is irradiated by the light, the photocurrent is significantly increased by about 2-3 times of that from pure TiO2 nanotubes. The band diagram of the ZnO/TiO2/Ti was proposed to interpret the photocurrent characteristics. Our result indicates that the ZnO/TiO2 can be excellent candidate semiconductor material for the photoelectrochemical energy transfer.
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spelling doaj.art-1f490de736b343139206a49cd44626d42022-12-22T02:10:21ZengAIP Publishing LLCAIP Advances2158-32262019-03-0193035237035237-510.1063/1.5090306075903ADVPhotoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctionsFang Wang0Dengji Yu1Jun Dai2Department of Physics, College of Science, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaDepartment of Physics, College of Science, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaDepartment of Physics, College of Science, Jiangsu University of Science and Technology, Zhenjiang 212003, ChinaIn this paper, TiO2 nanotubes are fabricated on Ti foils by anodic oxidation, a layer of ZnO nanorod arrays is further deposited on the TiO2 nanotube without seed layer by a hydrothermal method at different Zn2+ concentration. The result shows that the ZnO nanorods mainly present needle-like structure and the density of the nanorods increases with the Zn2+ concentration. The PL of the ZnO nanorods show that there are defect levels formed in the ZnO nanorods. When the ZnO/TiO2 heterostructure is irradiated by the light, the photocurrent is significantly increased by about 2-3 times of that from pure TiO2 nanotubes. The band diagram of the ZnO/TiO2/Ti was proposed to interpret the photocurrent characteristics. Our result indicates that the ZnO/TiO2 can be excellent candidate semiconductor material for the photoelectrochemical energy transfer.http://dx.doi.org/10.1063/1.5090306
spellingShingle Fang Wang
Dengji Yu
Jun Dai
Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions
AIP Advances
title Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions
title_full Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions
title_fullStr Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions
title_full_unstemmed Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions
title_short Photoelectrochemical characteristics of ZnO/ TiO2 nanoheterojunctions
title_sort photoelectrochemical characteristics of zno tio2 nanoheterojunctions
url http://dx.doi.org/10.1063/1.5090306
work_keys_str_mv AT fangwang photoelectrochemicalcharacteristicsofznotio2nanoheterojunctions
AT dengjiyu photoelectrochemicalcharacteristicsofznotio2nanoheterojunctions
AT jundai photoelectrochemicalcharacteristicsofznotio2nanoheterojunctions