Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin

Commercial kaolin from a Polish deposit has been examined as a low-cost adsorbent for effluent remediation using five cationic and five anionic industrial dyes. Methylene Blue dye was also used as a reference. The anionic dyes studied showed no affinity towards the kaolin surface, whereas the experi...

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Main Authors: D. Ziólkowska, A. Shyichuk, I. Karwasz, M. Witkowska
Format: Article
Language:English
Published: SAGE Publications 2009-03-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/026361709789625306
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author D. Ziólkowska
A. Shyichuk
I. Karwasz
M. Witkowska
author_facet D. Ziólkowska
A. Shyichuk
I. Karwasz
M. Witkowska
author_sort D. Ziólkowska
collection DOAJ
description Commercial kaolin from a Polish deposit has been examined as a low-cost adsorbent for effluent remediation using five cationic and five anionic industrial dyes. Methylene Blue dye was also used as a reference. The anionic dyes studied showed no affinity towards the kaolin surface, whereas the experimental isotherms for the adsorption of the cationic dyes could all be well described by the Langmuir equation. The values of the adsorption capacity of kaolin towards the cationic dyes ranged from 4 mg/g to 29 mg/g, being probably dependent on the geometry of the dye molecules. The resulting degrees of decolourization attained values of 85–90% for initial dye concentrations in the range 6–20 mg/dm 3 and for kaolin loadings of 0.5–3 g/dm 3 . Adsorption of the cationic dyes onto kaolin increased at higher solution pH values.
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spelling doaj.art-1f4e22c72ff542fdb55972ddf190b3cd2024-03-02T16:20:50ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382009-03-012710.1260/026361709789625306Adsorption of Cationic and Anionic Dyes onto Commercial KaolinD. ZiólkowskaA. ShyichukI. KarwaszM. WitkowskaCommercial kaolin from a Polish deposit has been examined as a low-cost adsorbent for effluent remediation using five cationic and five anionic industrial dyes. Methylene Blue dye was also used as a reference. The anionic dyes studied showed no affinity towards the kaolin surface, whereas the experimental isotherms for the adsorption of the cationic dyes could all be well described by the Langmuir equation. The values of the adsorption capacity of kaolin towards the cationic dyes ranged from 4 mg/g to 29 mg/g, being probably dependent on the geometry of the dye molecules. The resulting degrees of decolourization attained values of 85–90% for initial dye concentrations in the range 6–20 mg/dm 3 and for kaolin loadings of 0.5–3 g/dm 3 . Adsorption of the cationic dyes onto kaolin increased at higher solution pH values.https://doi.org/10.1260/026361709789625306
spellingShingle D. Ziólkowska
A. Shyichuk
I. Karwasz
M. Witkowska
Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin
Adsorption Science & Technology
title Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin
title_full Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin
title_fullStr Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin
title_full_unstemmed Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin
title_short Adsorption of Cationic and Anionic Dyes onto Commercial Kaolin
title_sort adsorption of cationic and anionic dyes onto commercial kaolin
url https://doi.org/10.1260/026361709789625306
work_keys_str_mv AT dziolkowska adsorptionofcationicandanionicdyesontocommercialkaolin
AT ashyichuk adsorptionofcationicandanionicdyesontocommercialkaolin
AT ikarwasz adsorptionofcationicandanionicdyesontocommercialkaolin
AT mwitkowska adsorptionofcationicandanionicdyesontocommercialkaolin