The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hyd...
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Polish Academy of Sciences
2023-09-01
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Series: | Archives of Metallurgy and Materials |
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Online Access: | https://journals.pan.pl/Content/128442/PDF/AMM-2023-3-33-Ibrahim.pdf |
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author | M. Ibrahim W.M.W. Ibrahim M.M. Al B. Abdullah L.H. Mahamud M.N.N. Tajuddin N.F. Yahya |
author_facet | M. Ibrahim W.M.W. Ibrahim M.M. Al B. Abdullah L.H. Mahamud M.N.N. Tajuddin N.F. Yahya |
author_sort | M. Ibrahim |
collection | DOAJ |
description | The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H2O2) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu2+ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu2+ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m2/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions. |
first_indexed | 2024-03-11T23:55:45Z |
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id | doaj.art-1f72493691da42cd95bd9f344d4f7f29 |
institution | Directory Open Access Journal |
issn | 2300-1909 |
language | English |
last_indexed | 2024-03-11T23:55:45Z |
publishDate | 2023-09-01 |
publisher | Polish Academy of Sciences |
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series | Archives of Metallurgy and Materials |
spelling | doaj.art-1f72493691da42cd95bd9f344d4f7f292023-09-18T11:14:42ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092023-09-01vol. 68No 310771086https://doi.org/10.24425/amm.2023.145478The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ AdsorptionM. Ibrahim0https://orcid.org/0000-0001-7632-2717W.M.W. Ibrahim1https://orcid.org/0000-0002-6766-3541M.M. Al B. Abdullah2https://orcid.org/0000-0002-9779-8586L.H. Mahamud3https://orcid.org/0000-0002-6408-1095M.N.N. Tajuddin4https://orcid.org/0000-0002-4608-7530N.F. Yahya5https://orcid.org/0000-0002-5819-1618Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Tun Hussein Onn Malaysia, Faculty of Engineering Technology, Johor, MalaysiaThe performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H2O2) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu2+ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu2+ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m2/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions.https://journals.pan.pl/Content/128442/PDF/AMM-2023-3-33-Ibrahim.pdfmetakaolinalkali activated materialshydrogen peroxidealuminium powder and copper ions adsorption |
spellingShingle | M. Ibrahim W.M.W. Ibrahim M.M. Al B. Abdullah L.H. Mahamud M.N.N. Tajuddin N.F. Yahya The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption Archives of Metallurgy and Materials metakaolin alkali activated materials hydrogen peroxide aluminium powder and copper ions adsorption |
title | The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption |
title_full | The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption |
title_fullStr | The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption |
title_full_unstemmed | The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption |
title_short | The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption |
title_sort | influence of foaming agent towards metakaolin based alkali activated materials properties and cu2 adsorption |
topic | metakaolin alkali activated materials hydrogen peroxide aluminium powder and copper ions adsorption |
url | https://journals.pan.pl/Content/128442/PDF/AMM-2023-3-33-Ibrahim.pdf |
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