The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption

The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hyd...

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Main Authors: M. Ibrahim, W.M.W. Ibrahim, M.M. Al B. Abdullah, L.H. Mahamud, M.N.N. Tajuddin, N.F. Yahya
Format: Article
Language:English
Published: Polish Academy of Sciences 2023-09-01
Series:Archives of Metallurgy and Materials
Subjects:
Online Access:https://journals.pan.pl/Content/128442/PDF/AMM-2023-3-33-Ibrahim.pdf
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author M. Ibrahim
W.M.W. Ibrahim
M.M. Al B. Abdullah
L.H. Mahamud
M.N.N. Tajuddin
N.F. Yahya
author_facet M. Ibrahim
W.M.W. Ibrahim
M.M. Al B. Abdullah
L.H. Mahamud
M.N.N. Tajuddin
N.F. Yahya
author_sort M. Ibrahim
collection DOAJ
description The performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H2O2) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu2+ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu2+ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m2/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions.
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spelling doaj.art-1f72493691da42cd95bd9f344d4f7f292023-09-18T11:14:42ZengPolish Academy of SciencesArchives of Metallurgy and Materials2300-19092023-09-01vol. 68No 310771086https://doi.org/10.24425/amm.2023.145478The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ AdsorptionM. Ibrahim0https://orcid.org/0000-0001-7632-2717W.M.W. Ibrahim1https://orcid.org/0000-0002-6766-3541M.M. Al B. Abdullah2https://orcid.org/0000-0002-9779-8586L.H. Mahamud3https://orcid.org/0000-0002-6408-1095M.N.N. Tajuddin4https://orcid.org/0000-0002-4608-7530N.F. Yahya5https://orcid.org/0000-0002-5819-1618Universiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Center of Excellence Geopolymer & Green Technology (CeGeoGTech), 02600, Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Malaysia Perlis (UniMAP), Faculty of Chemical Engineering Technology, Taman Muhibbah, Jejawi, 02600 Arau, Perlis, MalaysiaUniversiti Tun Hussein Onn Malaysia, Faculty of Engineering Technology, Johor, MalaysiaThe performance of adsorbent synthesized by alkali activation of aluminosilicate precursor metakaolin with sodium hydroxide (NaOH) and sodium silicate (Na2SiO3) as well as the foaming agent was studied for copper ions adsorption from aqueous solution. This paper investigated the effect of adding hydrogen peroxide (H2O2) and aluminium powder as foaming agents to an alkali activated materials slurry. The experimental range included 0.50 wt%, 0.75 wt%, and 1.00 wt% hydrogen peroxide and 0.02 wt%, 0.04 wt%, and 0.06 wt% aluminium powder. A control sample without a foaming agent was also created for comparison. The specific surface area, water absorption, density, compressive strength and microstructure of metakaolin based alkali activated materials were evaluated. The adsorption capability of Cu2+ with addition of hydrogen peroxide and aluminium powder was then tested. Results indicate hydrogen peroxide addition had superior pore size distribution and homogeneous porosity than aluminium powder, implying improved copper ion elimination. Cu2+ adsorption capability reached 98% with 0.75 wt% hydrogen peroxide and 24.6076 m2/g surface area. The results demonstrating that low cost metakaolin-based AAMs are the most effective adsorbent for removing copper ions.https://journals.pan.pl/Content/128442/PDF/AMM-2023-3-33-Ibrahim.pdfmetakaolinalkali activated materialshydrogen peroxidealuminium powder and copper ions adsorption
spellingShingle M. Ibrahim
W.M.W. Ibrahim
M.M. Al B. Abdullah
L.H. Mahamud
M.N.N. Tajuddin
N.F. Yahya
The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
Archives of Metallurgy and Materials
metakaolin
alkali activated materials
hydrogen peroxide
aluminium powder and copper ions adsorption
title The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
title_full The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
title_fullStr The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
title_full_unstemmed The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
title_short The Influence of Foaming Agent Towards Metakaolin Based Alkali Activated Materials Properties and Cu2+ Adsorption
title_sort influence of foaming agent towards metakaolin based alkali activated materials properties and cu2 adsorption
topic metakaolin
alkali activated materials
hydrogen peroxide
aluminium powder and copper ions adsorption
url https://journals.pan.pl/Content/128442/PDF/AMM-2023-3-33-Ibrahim.pdf
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