Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism
The global consumption of raw materials has shifted from the use of non-renewable materials to renewable materials. Studies on greener epoxidation by using vegetable oils to produce eco-friendly epoxides have also increased. In this study, the epoxidation of palm oleic acid was carried out by in sit...
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| Format: | Article |
| Language: | English |
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Croatian Society of Chemical Engineers
2022-03-01
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| Series: | Kemija u Industriji |
| Subjects: | |
| Online Access: | http://silverstripe.fkit.hr/kui/assets/Uploads/11-209-214-KUI-03-04-2022.pdf |
| _version_ | 1818445968506355712 |
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| author | Intan Suhada Azmi Muhammad Hazim Abu Bakar Danial Nuruddin Azlan Raofuddin Hamzah Hafizuddin Habri Mohamad Heiry Mohd Azmi Mohd Jumain Jalil |
| author_facet | Intan Suhada Azmi Muhammad Hazim Abu Bakar Danial Nuruddin Azlan Raofuddin Hamzah Hafizuddin Habri Mohamad Heiry Mohd Azmi Mohd Jumain Jalil |
| author_sort | Intan Suhada Azmi |
| collection | DOAJ |
| description | The global consumption of raw materials has shifted from the use of non-renewable materials to renewable materials. Studies on greener epoxidation by using vegetable oils to produce eco-friendly epoxides have also increased. In this study, the epoxidation of palm oleic acid was carried out by in situ generated performic acid. Fourier transform infrared spectroscopy of the products was conducted to confirm the success of the epoxidation. Lastly, a mathematical model was developed using the numerical integration of the 4th order Runge–Kutta method, and the results showed good agreement between the simulation and experimental data, which validates the kinetic model. |
| first_indexed | 2024-12-14T19:40:15Z |
| format | Article |
| id | doaj.art-1f7c9d2b72754ee6beef42efacee8cec |
| institution | Directory Open Access Journal |
| issn | 0022-9830 1334-9090 |
| language | English |
| last_indexed | 2024-12-14T19:40:15Z |
| publishDate | 2022-03-01 |
| publisher | Croatian Society of Chemical Engineers |
| record_format | Article |
| series | Kemija u Industriji |
| spelling | doaj.art-1f7c9d2b72754ee6beef42efacee8cec2022-12-21T22:49:43ZengCroatian Society of Chemical EngineersKemija u Industriji0022-98301334-90902022-03-01713-420921410.15255/KUI.2021.024Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid MechanismIntan Suhada Azmi0Muhammad Hazim Abu Bakar1Danial Nuruddin Azlan Raofuddin2Hamzah Hafizuddin Habri3Mohamad Heiry Mohd Azmi4Mohd Jumain Jalil5School of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, MalaysiaSchool of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, Cawangan Johor, Kampus Pasir Gudang, 81 750 Masai, Johor, MalaysiaSchool of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Kampus Permatang Pauh, 13 500 Permatang Pauh, Pulau Pinang, MalaysiaSchool of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Kampus Permatang Pauh, 13 500 Permatang Pauh, Pulau Pinang, MalaysiaSchool of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Kampus Permatang Pauh, 13 500 Permatang Pauh, Pulau Pinang, MalaysiaSchool of Chemical Engineering, College of Engineering, Universiti Teknologi MARA, Cawangan Pulau Pinang, Kampus Permatang Pauh, 13 500 Permatang Pauh, Pulau Pinang, MalaysiaThe global consumption of raw materials has shifted from the use of non-renewable materials to renewable materials. Studies on greener epoxidation by using vegetable oils to produce eco-friendly epoxides have also increased. In this study, the epoxidation of palm oleic acid was carried out by in situ generated performic acid. Fourier transform infrared spectroscopy of the products was conducted to confirm the success of the epoxidation. Lastly, a mathematical model was developed using the numerical integration of the 4th order Runge–Kutta method, and the results showed good agreement between the simulation and experimental data, which validates the kinetic model.http://silverstripe.fkit.hr/kui/assets/Uploads/11-209-214-KUI-03-04-2022.pdfepoxidationvegetables oilpalm oil |
| spellingShingle | Intan Suhada Azmi Muhammad Hazim Abu Bakar Danial Nuruddin Azlan Raofuddin Hamzah Hafizuddin Habri Mohamad Heiry Mohd Azmi Mohd Jumain Jalil Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism Kemija u Industriji epoxidation vegetables oil palm oil |
| title | Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism |
| title_full | Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism |
| title_fullStr | Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism |
| title_full_unstemmed | Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism |
| title_short | Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism |
| title_sort | synthesis and kinetic model of oleic acid based epoxides by in situ peracid mechanism |
| topic | epoxidation vegetables oil palm oil |
| url | http://silverstripe.fkit.hr/kui/assets/Uploads/11-209-214-KUI-03-04-2022.pdf |
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