Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption
Activated carbon has been used to treat organic dyes in water systems; however, the adsorption capacity of the samples studied was limited by the specific surface area and influenced by the pH of the aqueous solution. In this study, a hybrid adsorbent consisting of a mixture (MCS) of activated chest...
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author | Jiahao An Nguyen Thi Hong Nhung Yaxuan Ding Hao Chen Chunlin He Xinpeng Wang Toyohisa Fujita |
author_facet | Jiahao An Nguyen Thi Hong Nhung Yaxuan Ding Hao Chen Chunlin He Xinpeng Wang Toyohisa Fujita |
author_sort | Jiahao An |
collection | DOAJ |
description | Activated carbon has been used to treat organic dyes in water systems; however, the adsorption capacity of the samples studied was limited by the specific surface area and influenced by the pH of the aqueous solution. In this study, a hybrid adsorbent consisting of a mixture (MCS) of activated chestnut shell biochar (CN) and pyrolyzed snail shell material (SS) was developed to solve this problem, with the waste snail shell samples being processed by pyrolysis and the chestnut shell samples chemically pretreated and then pyrolyzed. The BET and SEM results revealed that the SS had a mesoporous fluffy structure with a higher specific surface (1705 m<sup>2</sup>/g) and an average pore diameter of about 4.07 nm, providing a large number of sites for adsorption. In addition, XPS and FTIR results showed that the main component of SS was calcium oxide, and it also contained a certain amount of calcium carbonate, which not only provided an alkaline environment for the adsorption of biochar but also degradation and photocatalytic capabilities. The results showed that the MCS3-1 sample, obtained when CN and SS were mixed in the ratio of 3:1, had good capacity for adsorption for methylene blue (MB), with 1145 mg/g at an initial concentration of 1300 mg/L (92% removal rate). The adsorption behaviors were fitted with the pseudo-second-order kinetic model and Freundlich isotherm model, which indicated that the adsorption was multilayer chemisorption with a saturated adsorption capacity of 1635 mg/g. The photocatalytic capacity from the SS composition was about 89 mg/g, and the sorption of MB dye onto the sorbent reached equilibrium after 300 min. The results suggested that MCS3-1 has enormous potential for removing MB from wastewater. |
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language | English |
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spelling | doaj.art-1f7caa52bf524ee2b03a68bccc45bde22023-11-24T09:06:15ZengMDPI AGMaterials1996-19442022-11-011522822710.3390/ma15228227Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue AdsorptionJiahao An0Nguyen Thi Hong Nhung1Yaxuan Ding2Hao Chen3Chunlin He4Xinpeng Wang5Toyohisa Fujita6School of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaSchool of Resources, Environment and Materials, Guangxi University, Nanning 530004, ChinaActivated carbon has been used to treat organic dyes in water systems; however, the adsorption capacity of the samples studied was limited by the specific surface area and influenced by the pH of the aqueous solution. In this study, a hybrid adsorbent consisting of a mixture (MCS) of activated chestnut shell biochar (CN) and pyrolyzed snail shell material (SS) was developed to solve this problem, with the waste snail shell samples being processed by pyrolysis and the chestnut shell samples chemically pretreated and then pyrolyzed. The BET and SEM results revealed that the SS had a mesoporous fluffy structure with a higher specific surface (1705 m<sup>2</sup>/g) and an average pore diameter of about 4.07 nm, providing a large number of sites for adsorption. In addition, XPS and FTIR results showed that the main component of SS was calcium oxide, and it also contained a certain amount of calcium carbonate, which not only provided an alkaline environment for the adsorption of biochar but also degradation and photocatalytic capabilities. The results showed that the MCS3-1 sample, obtained when CN and SS were mixed in the ratio of 3:1, had good capacity for adsorption for methylene blue (MB), with 1145 mg/g at an initial concentration of 1300 mg/L (92% removal rate). The adsorption behaviors were fitted with the pseudo-second-order kinetic model and Freundlich isotherm model, which indicated that the adsorption was multilayer chemisorption with a saturated adsorption capacity of 1635 mg/g. The photocatalytic capacity from the SS composition was about 89 mg/g, and the sorption of MB dye onto the sorbent reached equilibrium after 300 min. The results suggested that MCS3-1 has enormous potential for removing MB from wastewater.https://www.mdpi.com/1996-1944/15/22/8227snail shellschestnutpyrolysisadsorptionmethylene blue |
spellingShingle | Jiahao An Nguyen Thi Hong Nhung Yaxuan Ding Hao Chen Chunlin He Xinpeng Wang Toyohisa Fujita Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption Materials snail shells chestnut pyrolysis adsorption methylene blue |
title | Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption |
title_full | Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption |
title_fullStr | Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption |
title_full_unstemmed | Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption |
title_short | Chestnut Shell-Activated Carbon Mixed with Pyrolytic Snail Shells for Methylene Blue Adsorption |
title_sort | chestnut shell activated carbon mixed with pyrolytic snail shells for methylene blue adsorption |
topic | snail shells chestnut pyrolysis adsorption methylene blue |
url | https://www.mdpi.com/1996-1944/15/22/8227 |
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