4-Methyl-3-nitropyridin-2-amine
In the title compound, C6H7N3O2, the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intramolecular N—H...O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H...N hydrogen bonds occur, resul...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809022582 |
| Summary: | In the title compound, C6H7N3O2, the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intramolecular N—H...O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H...N hydrogen bonds occur, resulting in R22(8) rings. The packing is stabilized by aromatic π–π stacking [centroid–centroid distance = 3.5666 (15) Å] and a short N—O...π contact is seen. |
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| ISSN: | 1600-5368 |