4-Methyl-3-nitropyridin-2-amine
In the title compound, C6H7N3O2, the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intramolecular N—H...O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H...N hydrogen bonds occur, resul...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809022582 |
| _version_ | 1818886969016451072 |
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| author | Misbahul Ain Khan M. Nawaz Tahir Abdul Qayyum Ather Maryam Shaheen Rauf Ahmad Khan |
| author_facet | Misbahul Ain Khan M. Nawaz Tahir Abdul Qayyum Ather Maryam Shaheen Rauf Ahmad Khan |
| author_sort | Misbahul Ain Khan |
| collection | DOAJ |
| description | In the title compound, C6H7N3O2, the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intramolecular N—H...O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H...N hydrogen bonds occur, resulting in R22(8) rings. The packing is stabilized by aromatic π–π stacking [centroid–centroid distance = 3.5666 (15) Å] and a short N—O...π contact is seen. |
| first_indexed | 2024-12-19T16:29:46Z |
| format | Article |
| id | doaj.art-1f7eb23b4c994652b4d7a35c8260820f |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:29:46Z |
| publishDate | 2009-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1f7eb23b4c994652b4d7a35c8260820f2022-12-21T20:14:15ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-07-01657o1615o161510.1107/S16005368090225824-Methyl-3-nitropyridin-2-amineMisbahul Ain KhanM. Nawaz TahirAbdul Qayyum AtherMaryam ShaheenRauf Ahmad KhanIn the title compound, C6H7N3O2, the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intramolecular N—H...O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H...N hydrogen bonds occur, resulting in R22(8) rings. The packing is stabilized by aromatic π–π stacking [centroid–centroid distance = 3.5666 (15) Å] and a short N—O...π contact is seen.http://scripts.iucr.org/cgi-bin/paper?S1600536809022582 |
| spellingShingle | Misbahul Ain Khan M. Nawaz Tahir Abdul Qayyum Ather Maryam Shaheen Rauf Ahmad Khan 4-Methyl-3-nitropyridin-2-amine Acta Crystallographica Section E |
| title | 4-Methyl-3-nitropyridin-2-amine |
| title_full | 4-Methyl-3-nitropyridin-2-amine |
| title_fullStr | 4-Methyl-3-nitropyridin-2-amine |
| title_full_unstemmed | 4-Methyl-3-nitropyridin-2-amine |
| title_short | 4-Methyl-3-nitropyridin-2-amine |
| title_sort | 4 methyl 3 nitropyridin 2 amine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809022582 |
| work_keys_str_mv | AT misbahulainkhan 4methyl3nitropyridin2amine AT mnawaztahir 4methyl3nitropyridin2amine AT abdulqayyumather 4methyl3nitropyridin2amine AT maryamshaheen 4methyl3nitropyridin2amine AT raufahmadkhan 4methyl3nitropyridin2amine |