[(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate
A new N-heterocyclic cationic rhodium(I) complex with a tetrafluoridoborate counter-anion, [Rh(C8H14N2)(C8H12)(C18H15P)]BF4, has been prepared and structurally characterized. The cationic complex exhibits a distorted square-planar environment around the rhodium(I) ion. Two connections are made from...
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International Union of Crystallography
2021-06-01
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314621005976 |
| _version_ | 1818450122355245056 |
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| author | Jeffrey A. Rood Chhatra B. Subedi John P. Risell Andrei V. Astashkin Edward Rajaseelan |
| author_facet | Jeffrey A. Rood Chhatra B. Subedi John P. Risell Andrei V. Astashkin Edward Rajaseelan |
| author_sort | Jeffrey A. Rood |
| collection | DOAJ |
| description | A new N-heterocyclic cationic rhodium(I) complex with a tetrafluoridoborate counter-anion, [Rh(C8H14N2)(C8H12)(C18H15P)]BF4, has been prepared and structurally characterized. The cationic complex exhibits a distorted square-planar environment around the rhodium(I) ion. Two connections are made from rhodium(I) to the carbon atom of an N-heterocylic carbene ligand and to the phosphorus atom of a triphenylphosphane ligand. The remaining two coordination sites are made via a bidentate interaction from the two olefinic bonds of cyclooctadiene to the rhodium(I) ion. The compound includes an out-sphere tetrafluoridoborate counter-anion. Within the crystal of the compound exist several weak intermolecular C—H...F interactions. |
| first_indexed | 2024-12-14T20:46:17Z |
| format | Article |
| id | doaj.art-1f89dcf4b06c438ca33671bb4ecf19f0 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-14T20:46:17Z |
| publishDate | 2021-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-1f89dcf4b06c438ca33671bb4ecf19f02022-12-21T22:48:01ZengInternational Union of CrystallographyIUCrData2414-31462021-06-0166x21059710.1107/S2414314621005976wm4147[(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborateJeffrey A. Rood0Chhatra B. Subedi1John P. Risell2Andrei V. Astashkin3Edward Rajaseelan4Department of Chemistry and Biochemistry, School of Science, Elizabethtown College, One Alpha Drive, Elizabethtown, PA 17022, USADepartment of Chemistry, Millersville University, Millersville, PA 17551, USADepartment of Chemistry, Millersville University, Millersville, PA 17551, USADepartment of Chemistry and Biochemistry, The University of Arizona, Tucson, AZ 85716, USADepartment of Chemistry, Millersville University, Millersville, PA 17551, USAA new N-heterocyclic cationic rhodium(I) complex with a tetrafluoridoborate counter-anion, [Rh(C8H14N2)(C8H12)(C18H15P)]BF4, has been prepared and structurally characterized. The cationic complex exhibits a distorted square-planar environment around the rhodium(I) ion. Two connections are made from rhodium(I) to the carbon atom of an N-heterocylic carbene ligand and to the phosphorus atom of a triphenylphosphane ligand. The remaining two coordination sites are made via a bidentate interaction from the two olefinic bonds of cyclooctadiene to the rhodium(I) ion. The compound includes an out-sphere tetrafluoridoborate counter-anion. Within the crystal of the compound exist several weak intermolecular C—H...F interactions.http://scripts.iucr.org/cgi-bin/paper?S2414314621005976crystal structurerhodiumn-heterocyclic carbenescationic complexes |
| spellingShingle | Jeffrey A. Rood Chhatra B. Subedi John P. Risell Andrei V. Astashkin Edward Rajaseelan [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate IUCrData crystal structure rhodium n-heterocyclic carbenes cationic complexes |
| title | [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate |
| title_full | [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate |
| title_fullStr | [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate |
| title_full_unstemmed | [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate |
| title_short | [(1,2,5,6-η)-Cycloocta-1,5-diene](1-ethyl-3-isopropyl-1,3-imidazol-2-ylidene)(triphenylphosphane)rhodium(I) tetrafluoridoborate |
| title_sort | 1 2 5 6 η cycloocta 1 5 diene 1 ethyl 3 isopropyl 1 3 imidazol 2 ylidene triphenylphosphane rhodium i tetrafluoridoborate |
| topic | crystal structure rhodium n-heterocyclic carbenes cationic complexes |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314621005976 |
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