Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate
The fabrication of stretchable conductive material through vapor phase polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT) is presented alongside a method to easily pattern these materials with nanosecond laser structuring. The devices were constructed from sheets of vapor phase polymerized P...
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MDPI AG
2020-07-01
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Series: | Polymers |
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Online Access: | https://www.mdpi.com/2073-4360/12/8/1654 |
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author | Zaid Aqrawe Christian Boehler Mahima Bansal Simon J. O’Carroll Maria Asplund Darren Svirskis |
author_facet | Zaid Aqrawe Christian Boehler Mahima Bansal Simon J. O’Carroll Maria Asplund Darren Svirskis |
author_sort | Zaid Aqrawe |
collection | DOAJ |
description | The fabrication of stretchable conductive material through vapor phase polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT) is presented alongside a method to easily pattern these materials with nanosecond laser structuring. The devices were constructed from sheets of vapor phase polymerized PEDOT doped with tosylate on pre-stretched elastomeric substrates followed by laser structuring to achieve the desired geometrical shape. Devices were characterized for electrical conductivity, morphology, and electrical integrity in response to externally applied strain. Fabricated PEDOT sheets displayed a conductivity of 53.1 ± 1.2 S cm<sup>−1</sup>; clear buckling in the PEDOT microstructure was observed as a result of pre-stretching the underlying elastomeric substrate; and the final stretchable electronic devices were able to remain electrically conductive with up to 100% of externally applied strain. The described polymerization and fabrication steps achieve highly processable and patternable functional conductive polymer films, which are suitable for stretchable electronics due to their ability to withstand externally applied strains of up to 100%. |
first_indexed | 2024-03-10T18:12:44Z |
format | Article |
id | doaj.art-1f90e53df47949b2aafdd4ada00d8611 |
institution | Directory Open Access Journal |
issn | 2073-4360 |
language | English |
last_indexed | 2024-03-10T18:12:44Z |
publishDate | 2020-07-01 |
publisher | MDPI AG |
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series | Polymers |
spelling | doaj.art-1f90e53df47949b2aafdd4ada00d86112023-11-20T07:55:29ZengMDPI AGPolymers2073-43602020-07-01128165410.3390/polym12081654Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/TosylateZaid Aqrawe0Christian Boehler1Mahima Bansal2Simon J. O’Carroll3Maria Asplund4Darren Svirskis5Department of Anatomy & Medical Imaging, School of Medical Sciences, University of Auckland, Auckland 1023, New ZealandDepartment of Microsystems Engineering (IMTEK) and BrainLinks-BrainTools Center, University of Freiburg, 79110 Freiburg, GermanySchool of Pharmacy, University of Auckland, Auckland 1023, New ZealandDepartment of Anatomy & Medical Imaging, School of Medical Sciences, University of Auckland, Auckland 1023, New ZealandDepartment of Microsystems Engineering (IMTEK) and BrainLinks-BrainTools Center, University of Freiburg, 79110 Freiburg, GermanySchool of Pharmacy, University of Auckland, Auckland 1023, New ZealandThe fabrication of stretchable conductive material through vapor phase polymerization of poly(3,4-ethylenedioxythiophene) (PEDOT) is presented alongside a method to easily pattern these materials with nanosecond laser structuring. The devices were constructed from sheets of vapor phase polymerized PEDOT doped with tosylate on pre-stretched elastomeric substrates followed by laser structuring to achieve the desired geometrical shape. Devices were characterized for electrical conductivity, morphology, and electrical integrity in response to externally applied strain. Fabricated PEDOT sheets displayed a conductivity of 53.1 ± 1.2 S cm<sup>−1</sup>; clear buckling in the PEDOT microstructure was observed as a result of pre-stretching the underlying elastomeric substrate; and the final stretchable electronic devices were able to remain electrically conductive with up to 100% of externally applied strain. The described polymerization and fabrication steps achieve highly processable and patternable functional conductive polymer films, which are suitable for stretchable electronics due to their ability to withstand externally applied strains of up to 100%.https://www.mdpi.com/2073-4360/12/8/1654conducting polymersvapor phase polymerizationPDMSelastomeric |
spellingShingle | Zaid Aqrawe Christian Boehler Mahima Bansal Simon J. O’Carroll Maria Asplund Darren Svirskis Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate Polymers conducting polymers vapor phase polymerization PDMS elastomeric |
title | Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate |
title_full | Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate |
title_fullStr | Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate |
title_full_unstemmed | Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate |
title_short | Stretchable Electronics Based on Laser Structured, Vapor Phase Polymerized PEDOT/Tosylate |
title_sort | stretchable electronics based on laser structured vapor phase polymerized pedot tosylate |
topic | conducting polymers vapor phase polymerization PDMS elastomeric |
url | https://www.mdpi.com/2073-4360/12/8/1654 |
work_keys_str_mv | AT zaidaqrawe stretchableelectronicsbasedonlaserstructuredvaporphasepolymerizedpedottosylate AT christianboehler stretchableelectronicsbasedonlaserstructuredvaporphasepolymerizedpedottosylate AT mahimabansal stretchableelectronicsbasedonlaserstructuredvaporphasepolymerizedpedottosylate AT simonjocarroll stretchableelectronicsbasedonlaserstructuredvaporphasepolymerizedpedottosylate AT mariaasplund stretchableelectronicsbasedonlaserstructuredvaporphasepolymerizedpedottosylate AT darrensvirskis stretchableelectronicsbasedonlaserstructuredvaporphasepolymerizedpedottosylate |