Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics

Due to the extrinsic contribution of domain wall motions to electro-strains, the incompatibility of the large electro-strain with a low hysteresis in piezoelectric ceramics is a stumbling block for designing high-performance piezoelectrical actuators. Herein, we report a critical state in relaxor fe...

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Main Authors: Xiang Xia, Xingan Jiang, Jiangtao Zeng, Liaoying Zheng, Zhenyong Man, Huarong Zeng, Guorong Li
Format: Article
Language:English
Published: Elsevier 2021-09-01
Series:Journal of Materiomics
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2352847821000150
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author Xiang Xia
Xingan Jiang
Jiangtao Zeng
Liaoying Zheng
Zhenyong Man
Huarong Zeng
Guorong Li
author_facet Xiang Xia
Xingan Jiang
Jiangtao Zeng
Liaoying Zheng
Zhenyong Man
Huarong Zeng
Guorong Li
author_sort Xiang Xia
collection DOAJ
description Due to the extrinsic contribution of domain wall motions to electro-strains, the incompatibility of the large electro-strain with a low hysteresis in piezoelectric ceramics is a stumbling block for designing high-performance piezoelectrical actuators. Herein, we report a critical state in relaxor ferroelectric systems enables to enhance the electro-strain and to reduce the hysteresis simultaneously. A room temperature ergodic relaxor state dominated by nanodomains with different local symmetries can be obtained by introducing Bi(Zn1/2Ti1/2)TiO3 into 0.73 Pb(Mg1/3Nb2/3)O3-0.27PbTiO3 matrix. Like the morphotropic phase boundary (MPB) in ferroelectrics, the coexistence of different local symmetries is capable of facilitating the transition from the ergodic relaxor state to the ferroelectric under the applied field due to the ease of polarization rotation, thereby leading to a giant electro-stain (0.24%) under an electric field of 50 kV/cm. Furthermore, the field-induced ferroelectric state with the long-range ferroelectric order can spontaneously reverse back to the initial ergodic relaxor state during unloading the electric field, which contributes to a low hysteresis (15.4%). The present work not only introduces a solid solution system with excellent electro-strain properties but also affords a guidance for manipulating the electro-strain behavior by modulating phase structures and domain configurations of piezoelectric ceramics.
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spelling doaj.art-1facfdd201f54b538c198abee8a14f9a2023-09-02T07:38:20ZengElsevierJournal of Materiomics2352-84782021-09-017511431152Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramicsXiang Xia0Xingan Jiang1Jiangtao Zeng2Liaoying Zheng3Zhenyong Man4Huarong Zeng5Guorong Li6Key Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, ChinaSchool of Aerospace Engineering, Beijing Institute of Technology, Beijing, 100081, ChinaKey Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, ChinaKey Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, ChinaKey Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, ChinaKey Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, ChinaKey Laboratory of Inorganic Functional Material and Device, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China; Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China; Corresponding author. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.Due to the extrinsic contribution of domain wall motions to electro-strains, the incompatibility of the large electro-strain with a low hysteresis in piezoelectric ceramics is a stumbling block for designing high-performance piezoelectrical actuators. Herein, we report a critical state in relaxor ferroelectric systems enables to enhance the electro-strain and to reduce the hysteresis simultaneously. A room temperature ergodic relaxor state dominated by nanodomains with different local symmetries can be obtained by introducing Bi(Zn1/2Ti1/2)TiO3 into 0.73 Pb(Mg1/3Nb2/3)O3-0.27PbTiO3 matrix. Like the morphotropic phase boundary (MPB) in ferroelectrics, the coexistence of different local symmetries is capable of facilitating the transition from the ergodic relaxor state to the ferroelectric under the applied field due to the ease of polarization rotation, thereby leading to a giant electro-stain (0.24%) under an electric field of 50 kV/cm. Furthermore, the field-induced ferroelectric state with the long-range ferroelectric order can spontaneously reverse back to the initial ergodic relaxor state during unloading the electric field, which contributes to a low hysteresis (15.4%). The present work not only introduces a solid solution system with excellent electro-strain properties but also affords a guidance for manipulating the electro-strain behavior by modulating phase structures and domain configurations of piezoelectric ceramics.http://www.sciencedirect.com/science/article/pii/S2352847821000150Electro-strainHysteresisRelaxor ferroelectricDomainLocal symmetry
spellingShingle Xiang Xia
Xingan Jiang
Jiangtao Zeng
Liaoying Zheng
Zhenyong Man
Huarong Zeng
Guorong Li
Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics
Journal of Materiomics
Electro-strain
Hysteresis
Relaxor ferroelectric
Domain
Local symmetry
title Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics
title_full Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics
title_fullStr Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics
title_full_unstemmed Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics
title_short Critical state to achieve a giant electric field-induced strain with a low hysteresis in relaxor piezoelectric ceramics
title_sort critical state to achieve a giant electric field induced strain with a low hysteresis in relaxor piezoelectric ceramics
topic Electro-strain
Hysteresis
Relaxor ferroelectric
Domain
Local symmetry
url http://www.sciencedirect.com/science/article/pii/S2352847821000150
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