Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds
New composites with high energy dissipation and self-healing properties are required for structural materials, textiles, and protective equipment. This paper proposes a cross-scale strategy to design sacrificial bond composites (SBCs) using non-linear adhesive materials, like self-assembled proteins...
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Format: | Article |
Language: | English |
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Elsevier
2023-09-01
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Series: | Materials & Design |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S0264127523006986 |
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author | Vanessa Restrepo Ramses V. Martinez |
author_facet | Vanessa Restrepo Ramses V. Martinez |
author_sort | Vanessa Restrepo |
collection | DOAJ |
description | New composites with high energy dissipation and self-healing properties are required for structural materials, textiles, and protective equipment. This paper proposes a cross-scale strategy to design sacrificial bond composites (SBCs) using non-linear adhesive materials, like self-assembled proteins or mechanical adhesives, placed between opposite-facing magnets. Upon external loads, SBCs effectively dissipate deformation energy across their sacrificial bond interfaces following a biomimetic toughening mechanism similar to nacre’s. When the external load breaks the sacrificial bonds of a SBC, the opposite-facing magnets brings together the separated interface, allowing the reforming of its sacrificial bonds and the self-repairing of the composite after sustaining large strains. After mechanical failure at 600% strain, the consensus tetratricopeptide repeat (CTPR) protein films allows protein-based SBCs to recover 70% of their original tensile strength after letting their sacrificial bonds to reassemble for 1 h, at room temperature, in the presence of moisture. Mechanical adhesive-based SBCs, after their mechanical failure at 325% strain, are able to self-repair faster, regaining 85% of their tensile strength in less than 1 s. As a proof of concept, we demonstrate the fabrication of a reusable and lightweight fall arrest system exploiting mechanical adhesive interfaces and a protein-polyester yarn for the creation of high-energy dissipating textiles. |
first_indexed | 2024-03-11T21:15:40Z |
format | Article |
id | doaj.art-1fbd5c6f62cc47d6b977d6c3581f65f4 |
institution | Directory Open Access Journal |
issn | 0264-1275 |
language | English |
last_indexed | 2024-03-11T21:15:40Z |
publishDate | 2023-09-01 |
publisher | Elsevier |
record_format | Article |
series | Materials & Design |
spelling | doaj.art-1fbd5c6f62cc47d6b977d6c3581f65f42023-09-29T04:43:40ZengElsevierMaterials & Design0264-12752023-09-01233112283Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bondsVanessa Restrepo0Ramses V. Martinez1J. Mike Walker ’66 Department of Mechanical Engineering, Texas A&M University, 3123 TAMU, College Station, TX 77843-3123, USA; Corresponding author.School of Industrial Engineering, Purdue University, 315 N. Grant Street, West Lafayette, IN 47907, USA; Weldon School of Biomedical Engineering, Purdue University, 206 S. Martin Jischke Drive, West Lafayette, IN 47907, USANew composites with high energy dissipation and self-healing properties are required for structural materials, textiles, and protective equipment. This paper proposes a cross-scale strategy to design sacrificial bond composites (SBCs) using non-linear adhesive materials, like self-assembled proteins or mechanical adhesives, placed between opposite-facing magnets. Upon external loads, SBCs effectively dissipate deformation energy across their sacrificial bond interfaces following a biomimetic toughening mechanism similar to nacre’s. When the external load breaks the sacrificial bonds of a SBC, the opposite-facing magnets brings together the separated interface, allowing the reforming of its sacrificial bonds and the self-repairing of the composite after sustaining large strains. After mechanical failure at 600% strain, the consensus tetratricopeptide repeat (CTPR) protein films allows protein-based SBCs to recover 70% of their original tensile strength after letting their sacrificial bonds to reassemble for 1 h, at room temperature, in the presence of moisture. Mechanical adhesive-based SBCs, after their mechanical failure at 325% strain, are able to self-repair faster, regaining 85% of their tensile strength in less than 1 s. As a proof of concept, we demonstrate the fabrication of a reusable and lightweight fall arrest system exploiting mechanical adhesive interfaces and a protein-polyester yarn for the creation of high-energy dissipating textiles.http://www.sciencedirect.com/science/article/pii/S0264127523006986Sacrificial bondsSelf-repairing interfacesSelf-assembled proteinsMechanical adhesivesEnergy-dissipating composite |
spellingShingle | Vanessa Restrepo Ramses V. Martinez Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds Materials & Design Sacrificial bonds Self-repairing interfaces Self-assembled proteins Mechanical adhesives Energy-dissipating composite |
title | Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds |
title_full | Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds |
title_fullStr | Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds |
title_full_unstemmed | Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds |
title_short | Cross-scale design of energy dissipative composites using self-repairing interfaces based on sacrificial bonds |
title_sort | cross scale design of energy dissipative composites using self repairing interfaces based on sacrificial bonds |
topic | Sacrificial bonds Self-repairing interfaces Self-assembled proteins Mechanical adhesives Energy-dissipating composite |
url | http://www.sciencedirect.com/science/article/pii/S0264127523006986 |
work_keys_str_mv | AT vanessarestrepo crossscaledesignofenergydissipativecompositesusingselfrepairinginterfacesbasedonsacrificialbonds AT ramsesvmartinez crossscaledesignofenergydissipativecompositesusingselfrepairinginterfacesbasedonsacrificialbonds |