Structural proof of a [C–F–C]+ fluoronium cation
Unlike other halogen atoms, the ability for fluorine to exist in a [C–X–C]+ connectivity pattern has only been shown in spectroscopic studies. Here the authors present a single crystal structure of a fluoronium cation, characterized by X-ray diffraction.
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2021-09-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-021-25592-6 |
| _version_ | 1818432597932376064 |
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| author | Kurt F. Hoffmann Anja Wiesner Carsten Müller Simon Steinhauer Helmut Beckers Muhammad Kazim Cody Ross Pitts Thomas Lectka Sebastian Riedel |
| author_facet | Kurt F. Hoffmann Anja Wiesner Carsten Müller Simon Steinhauer Helmut Beckers Muhammad Kazim Cody Ross Pitts Thomas Lectka Sebastian Riedel |
| author_sort | Kurt F. Hoffmann |
| collection | DOAJ |
| description | Unlike other halogen atoms, the ability for fluorine to exist in a [C–X–C]+ connectivity pattern has only been shown in spectroscopic studies. Here the authors present a single crystal structure of a fluoronium cation, characterized by X-ray diffraction. |
| first_indexed | 2024-12-14T16:07:44Z |
| format | Article |
| id | doaj.art-1fc5f35ca862425bb3db149b24dbcb96 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-14T16:07:44Z |
| publishDate | 2021-09-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-1fc5f35ca862425bb3db149b24dbcb962022-12-21T22:55:03ZengNature PortfolioNature Communications2041-17232021-09-011211710.1038/s41467-021-25592-6Structural proof of a [C–F–C]+ fluoronium cationKurt F. Hoffmann0Anja Wiesner1Carsten Müller2Simon Steinhauer3Helmut Beckers4Muhammad Kazim5Cody Ross Pitts6Thomas Lectka7Sebastian Riedel8Fachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität BerlinFachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität BerlinFachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität BerlinFachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität BerlinFachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität BerlinDepartment of Chemistry, Johns Hopkins UniversityDepartment of Chemistry, Johns Hopkins UniversityDepartment of Chemistry, Johns Hopkins UniversityFachbereich Biologie, Chemie, Pharmazie, Institut für Chemie und Biochemie – Anorganische Chemie, Freie Universität BerlinUnlike other halogen atoms, the ability for fluorine to exist in a [C–X–C]+ connectivity pattern has only been shown in spectroscopic studies. Here the authors present a single crystal structure of a fluoronium cation, characterized by X-ray diffraction.https://doi.org/10.1038/s41467-021-25592-6 |
| spellingShingle | Kurt F. Hoffmann Anja Wiesner Carsten Müller Simon Steinhauer Helmut Beckers Muhammad Kazim Cody Ross Pitts Thomas Lectka Sebastian Riedel Structural proof of a [C–F–C]+ fluoronium cation Nature Communications |
| title | Structural proof of a [C–F–C]+ fluoronium cation |
| title_full | Structural proof of a [C–F–C]+ fluoronium cation |
| title_fullStr | Structural proof of a [C–F–C]+ fluoronium cation |
| title_full_unstemmed | Structural proof of a [C–F–C]+ fluoronium cation |
| title_short | Structural proof of a [C–F–C]+ fluoronium cation |
| title_sort | structural proof of a c f c fluoronium cation |
| url | https://doi.org/10.1038/s41467-021-25592-6 |
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