Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate
In the title compound, [Co(C9H8NO3)(C12H8N2)2(H2O)]NO3·H2O, the CoII atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The uncoordinated O atom of the hipp...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2010-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536810040602 |
| _version_ | 1818913516328845312 |
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| author | Gui-Quan Guo Ji-Hua Deng Jing Chen |
| author_facet | Gui-Quan Guo Ji-Hua Deng Jing Chen |
| author_sort | Gui-Quan Guo |
| collection | DOAJ |
| description | In the title compound, [Co(C9H8NO3)(C12H8N2)2(H2O)]NO3·H2O, the CoII atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intramolecular hydrogen bond to the coordinated water molecule. The crystal packing is stabilized by intermolecular O—H...O hydrogen bonds involving the Hc anions, the coordinated water molecule, the nitrate anion and the uncoordinated water molecule. |
| first_indexed | 2024-12-19T23:31:44Z |
| format | Article |
| id | doaj.art-1fdabd1d8fb3443ba46b4f41c3a083d7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:31:44Z |
| publishDate | 2010-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-1fdabd1d8fb3443ba46b4f41c3a083d72022-12-21T20:01:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-11-016611m1415m141610.1107/S1600536810040602Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrateGui-Quan GuoJi-Hua DengJing ChenIn the title compound, [Co(C9H8NO3)(C12H8N2)2(H2O)]NO3·H2O, the CoII atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octahedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intramolecular hydrogen bond to the coordinated water molecule. The crystal packing is stabilized by intermolecular O—H...O hydrogen bonds involving the Hc anions, the coordinated water molecule, the nitrate anion and the uncoordinated water molecule.http://scripts.iucr.org/cgi-bin/paper?S1600536810040602 |
| spellingShingle | Gui-Quan Guo Ji-Hua Deng Jing Chen Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate Acta Crystallographica Section E |
| title | Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate |
| title_full | Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate |
| title_fullStr | Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate |
| title_full_unstemmed | Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate |
| title_short | Aqua(hippurato)bis(1,10-phenanthroline)cobalt(II) nitrate monohydrate |
| title_sort | aqua hippurato bis 1 10 phenanthroline cobalt ii nitrate monohydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536810040602 |
| work_keys_str_mv | AT guiquanguo aquahippuratobis110phenanthrolinecobaltiinitratemonohydrate AT jihuadeng aquahippuratobis110phenanthrolinecobaltiinitratemonohydrate AT jingchen aquahippuratobis110phenanthrolinecobaltiinitratemonohydrate |