Improving Photoelectrochemical Activity of Magnetron-Sputtered Double-Layer Tungsten Trioxide Photoanodes by Irradiation with Intense Pulsed Ion Beams
The photoelectrochemical (PEC) activity of metal oxide photoelectrodes for water-splitting applications can be boosted in several different ways. In this study, we showed that PEC activity can be significantly improved with a double-layer (crystalline-amorphous) configuration of WO<sub>3</s...
| Autores principales: | , , , |
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| Formato: | Artículo |
| Lenguaje: | English |
| Publicado: |
MDPI AG
2022-07-01
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| Colección: | Nanomaterials |
| Materias: | |
| Acceso en línea: | https://www.mdpi.com/2079-4991/12/15/2639 |
| Sumario: | The photoelectrochemical (PEC) activity of metal oxide photoelectrodes for water-splitting applications can be boosted in several different ways. In this study, we showed that PEC activity can be significantly improved with a double-layer (crystalline-amorphous) configuration of WO<sub>3</sub> thin films irradiated with intense pulsed ion beams (IPIB) of a nanosecond duration. It was found that IPIB irradiation promotes the formation of crystalline and sponge-like WO<sub>3</sub> structures on the surface. Due to an increase in the active surface and light scattering in irradiated samples, photocurrent generation increased by ~80% at 1.23 reversible hydrogen electrodes (RHE). |
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| ISSN: | 2079-4991 |