Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies
A review paper on Au(III) cyclometallated compounds with 2-arylpyridines (2-phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2-phenylsulfanylpyridine, 2-anilinopyridine, 2-(naphth-2-yl)pyridine, 2-(9,9-dialkylfluoren-2-yl)pyridines, 2-(dibenzofuran-4-yl)pyridine, and their der...
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-02-01
|
| Series: | Inorganics |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2304-6740/11/3/100 |
| _version_ | 1797611076852908032 |
|---|---|
| author | Leszek Pazderski Pavel A. Abramov |
| author_facet | Leszek Pazderski Pavel A. Abramov |
| author_sort | Leszek Pazderski |
| collection | DOAJ |
| description | A review paper on Au(III) cyclometallated compounds with 2-arylpyridines (2-phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2-phenylsulfanylpyridine, 2-anilinopyridine, 2-(naphth-2-yl)pyridine, 2-(9,9-dialkylfluoren-2-yl)pyridines, 2-(dibenzofuran-4-yl)pyridine, and their derivatives) and their analogues (2-arylquinolines, 1- and 3-arylisoquinolines, 7,8-benzoquinoline), with 113 references. A total of 554 species, containing κ<sup>2</sup>-N(1),C(6′)*-Au(III), or analogous moiety (i.e., chelated by nitrogen of the pyridine-like ring and the deprotonated <i>ortho</i>- carbon of the phenyl-like ring) and, thus, possessing a character intermediate between metal complexes and organometallics, studied in the years 1989–2022 by NMR spectroscopy and/or single crystal X-ray diffraction (207 X-ray structures), are described. The compounds for which biological or catalytic activity and the luminescence properties were studied are also quoted. |
| first_indexed | 2024-03-11T06:23:46Z |
| format | Article |
| id | doaj.art-2004b9248e414659acb2fe85acd5ece0 |
| institution | Directory Open Access Journal |
| issn | 2304-6740 |
| language | English |
| last_indexed | 2024-03-11T06:23:46Z |
| publishDate | 2023-02-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Inorganics |
| spelling | doaj.art-2004b9248e414659acb2fe85acd5ece02023-11-17T11:45:00ZengMDPI AGInorganics2304-67402023-02-0111310010.3390/inorganics11030100Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray StudiesLeszek Pazderski0Pavel A. Abramov1Faculty of Chemistry, Nicolaus Copernicus University, 7 Gagarina, 87100 Toruń, PolandNikolaev Institute of Inorganic Chemistry of the Russian Academy of Sciences, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, RussiaA review paper on Au(III) cyclometallated compounds with 2-arylpyridines (2-phenylpyridine, 2-benzylpyridine, 2-benzoylpyridine, 2-phenoxypyridine, 2-phenylsulfanylpyridine, 2-anilinopyridine, 2-(naphth-2-yl)pyridine, 2-(9,9-dialkylfluoren-2-yl)pyridines, 2-(dibenzofuran-4-yl)pyridine, and their derivatives) and their analogues (2-arylquinolines, 1- and 3-arylisoquinolines, 7,8-benzoquinoline), with 113 references. A total of 554 species, containing κ<sup>2</sup>-N(1),C(6′)*-Au(III), or analogous moiety (i.e., chelated by nitrogen of the pyridine-like ring and the deprotonated <i>ortho</i>- carbon of the phenyl-like ring) and, thus, possessing a character intermediate between metal complexes and organometallics, studied in the years 1989–2022 by NMR spectroscopy and/or single crystal X-ray diffraction (207 X-ray structures), are described. The compounds for which biological or catalytic activity and the luminescence properties were studied are also quoted.https://www.mdpi.com/2304-6740/11/3/100Au(III) compounds2-phenylpyridinecyclometallation<sup>15</sup>N NMRX-ray |
| spellingShingle | Leszek Pazderski Pavel A. Abramov Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies Inorganics Au(III) compounds 2-phenylpyridine cyclometallation <sup>15</sup>N NMR X-ray |
| title | Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies |
| title_full | Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies |
| title_fullStr | Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies |
| title_full_unstemmed | Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies |
| title_short | Au(III) Cyclometallated Compounds with 2-Arylpyridines and Their Derivatives or Analogues: 34 Years (1989–2022) of NMR and Single Crystal X-ray Studies |
| title_sort | au iii cyclometallated compounds with 2 arylpyridines and their derivatives or analogues 34 years 1989 2022 of nmr and single crystal x ray studies |
| topic | Au(III) compounds 2-phenylpyridine cyclometallation <sup>15</sup>N NMR X-ray |
| url | https://www.mdpi.com/2304-6740/11/3/100 |
| work_keys_str_mv | AT leszekpazderski auiiicyclometallatedcompoundswith2arylpyridinesandtheirderivativesoranalogues34years19892022ofnmrandsinglecrystalxraystudies AT pavelaabramov auiiicyclometallatedcompoundswith2arylpyridinesandtheirderivativesoranalogues34years19892022ofnmrandsinglecrystalxraystudies |