A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks

Towards the commercialisation of microbial fuel cell (MFC) technology, well-performing, cost-effective, and sustainable separators are being developed. Ceramic is one of the promising materials for this purpose. In this study, ceramic separators made of three different clay types were tested to inve...

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Main Authors: Jiseon You, Lauren Wallis, Nevena Radisavljevic, Grzegorz Pasternak, Vincenzo M. Sglavo, Martin M Hanczyc, John Greenman, Ioannis Ieropoulos
Format: Article
Language:English
Published: MDPI AG 2019-10-01
Series:Energies
Subjects:
Online Access:https://www.mdpi.com/1996-1073/12/21/4071
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author Jiseon You
Lauren Wallis
Nevena Radisavljevic
Grzegorz Pasternak
Vincenzo M. Sglavo
Martin M Hanczyc
John Greenman
Ioannis Ieropoulos
author_facet Jiseon You
Lauren Wallis
Nevena Radisavljevic
Grzegorz Pasternak
Vincenzo M. Sglavo
Martin M Hanczyc
John Greenman
Ioannis Ieropoulos
author_sort Jiseon You
collection DOAJ
description Towards the commercialisation of microbial fuel cell (MFC) technology, well-performing, cost-effective, and sustainable separators are being developed. Ceramic is one of the promising materials for this purpose. In this study, ceramic separators made of three different clay types were tested to investigate the effect of ceramic material properties on their performance. The best-performing ceramic separators were white ceramic-based spotty membranes, which produced maximum power outputs of 717.7 &#177; 29.9 &#181;W (white ceramic-based with brown spots, 71.8 W&#183;m<sup>&#8722;3</sup>) and 715.3 &#177; 73.0 &#181;W (white ceramic-based with red spots, 71.5 W&#183;m<sup>&#8722;3</sup>). For single material ceramic types, red ceramic separator generated the highest power output of 670.5 &#177; 64. 8 &#181;W (67.1 W&#183;m<sup>&#8722;3</sup>). Porosity investigation revealed that white and red ceramics are more porous and have smaller pores compared to brown ceramic. Brown ceramic separators underperformed initially but seem more favourable for long-term operation due to bigger pores and thus less tendency of membrane fouling. This study presents ways to enhance the function of ceramic separators in MFCs such as the novel spotty design as well as fine-tuning of porosity and pore size.
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spelling doaj.art-201580d9d73943248b51f036ee7395972022-12-22T03:19:30ZengMDPI AGEnergies1996-10732019-10-011221407110.3390/en12214071en12214071A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” BricksJiseon You0Lauren Wallis1Nevena Radisavljevic2Grzegorz Pasternak3Vincenzo M. Sglavo4Martin M Hanczyc5John Greenman6Ioannis Ieropoulos7Bristol BioEnergy Centre, University of the West of England, Bristol BS16 1QY, UKBristol BioEnergy Centre, University of the West of England, Bristol BS16 1QY, UKLaboratory for Artificial Biology, Department of Cellular, Computational and Integrative Biology (CIBIO), University of Trento, Via Sommarive 9, 38123 Povo TN, ItalyLaboratory for Artificial Biology, Department of Cellular, Computational and Integrative Biology (CIBIO), University of Trento, Via Sommarive 9, 38123 Povo TN, ItalyDepartment of Industrial Engineering, University of Trento, via Sommarive 9, 38123 Trento, ItalyLaboratory for Artificial Biology, Department of Cellular, Computational and Integrative Biology (CIBIO), University of Trento, Via Sommarive 9, 38123 Povo TN, ItalyBristol BioEnergy Centre, University of the West of England, Bristol BS16 1QY, UKBristol BioEnergy Centre, University of the West of England, Bristol BS16 1QY, UKTowards the commercialisation of microbial fuel cell (MFC) technology, well-performing, cost-effective, and sustainable separators are being developed. Ceramic is one of the promising materials for this purpose. In this study, ceramic separators made of three different clay types were tested to investigate the effect of ceramic material properties on their performance. The best-performing ceramic separators were white ceramic-based spotty membranes, which produced maximum power outputs of 717.7 &#177; 29.9 &#181;W (white ceramic-based with brown spots, 71.8 W&#183;m<sup>&#8722;3</sup>) and 715.3 &#177; 73.0 &#181;W (white ceramic-based with red spots, 71.5 W&#183;m<sup>&#8722;3</sup>). For single material ceramic types, red ceramic separator generated the highest power output of 670.5 &#177; 64. 8 &#181;W (67.1 W&#183;m<sup>&#8722;3</sup>). Porosity investigation revealed that white and red ceramics are more porous and have smaller pores compared to brown ceramic. Brown ceramic separators underperformed initially but seem more favourable for long-term operation due to bigger pores and thus less tendency of membrane fouling. This study presents ways to enhance the function of ceramic separators in MFCs such as the novel spotty design as well as fine-tuning of porosity and pore size.https://www.mdpi.com/1996-1073/12/21/4071microbial fuel celllow-cost ceramicsseparatormembraneporositypore sizewater absorptionmercury intrusion
spellingShingle Jiseon You
Lauren Wallis
Nevena Radisavljevic
Grzegorz Pasternak
Vincenzo M. Sglavo
Martin M Hanczyc
John Greenman
Ioannis Ieropoulos
A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks
Energies
microbial fuel cell
low-cost ceramics
separator
membrane
porosity
pore size
water absorption
mercury intrusion
title A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks
title_full A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks
title_fullStr A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks
title_full_unstemmed A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks
title_short A Comprehensive Study of Custom-Made Ceramic Separators for Microbial Fuel Cells: Towards “Living” Bricks
title_sort comprehensive study of custom made ceramic separators for microbial fuel cells towards living bricks
topic microbial fuel cell
low-cost ceramics
separator
membrane
porosity
pore size
water absorption
mercury intrusion
url https://www.mdpi.com/1996-1073/12/21/4071
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