Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites
The heterogeneous nucleation process of polypropylene (PP)/high density polyethylene (HDPE)/thermoplastic elastomer (POE) composites was realized through blending modification, and characterization techniques, including scanning electron microscopy, differential scanning calorimetry, X-ray diffracti...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
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De Gruyter
2024-04-01
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| Series: | e-Polymers |
| Subjects: | |
| Online Access: | https://doi.org/10.1515/epoly-2023-0164 |
| _version_ | 1827276361801138176 |
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| author | Ma Yulong Yang Kang Zhang Yi Wang Juheng Zeng Shu Huang Xiaoxiao |
| author_facet | Ma Yulong Yang Kang Zhang Yi Wang Juheng Zeng Shu Huang Xiaoxiao |
| author_sort | Ma Yulong |
| collection | DOAJ |
| description | The heterogeneous nucleation process of polypropylene (PP)/high density polyethylene (HDPE)/thermoplastic elastomer (POE) composites was realized through blending modification, and characterization techniques, including scanning electron microscopy, differential scanning calorimetry, X-ray diffraction, and dynamic mechanical analysis, were used to analyze the pattern of the impact of modified dicyclohexyl-terephthalamide (TMB-5) on the mechanical properties and thermal stability of the PP/HDPE/POE composites. The results indicated that the modified TMB-5 was advantageous to the improvement of the mechanical properties and thermal stability of the high-temperature (cooking temperature)-resistant PP/HDPE/POE composites. When the amount of added modified TMB-5 was 0.4%, the impact strength and tensile strength of the PP/HDPE/POE composites increased to 36.3 kJ/m2 and 31.7 MPa, respectively, which were, respectively, 99.5% and 8.5% higher than those of the materials prepared when the amount of added modified TMB was 0.1%. The materials had higher storage modulus in room-temperature and high-temperature environments: 2,438.2 MPa (room temperature), 1,103.9 MPa (120°C), and 1,054.8 MPa (140°C). In addition, the capability of the PP/HDPE/POE composites to crystallize was improved continuously, and the crystallinity increased considerably. At the same time, the crystallization and melting temperatures increased, β-crystal formation was induced, and glass transition temperature increased, thus effectively improving the mechanical properties and thermal stability of the high-temperature (cooking temperature)-resistant PP/HDPE/POE composites. |
| first_indexed | 2024-04-24T06:46:12Z |
| format | Article |
| id | doaj.art-20405aee737a4cfb9856e160907d0a7f |
| institution | Directory Open Access Journal |
| issn | 1618-7229 |
| language | English |
| last_indexed | 2024-04-24T06:46:12Z |
| publishDate | 2024-04-01 |
| publisher | De Gruyter |
| record_format | Article |
| series | e-Polymers |
| spelling | doaj.art-20405aee737a4cfb9856e160907d0a7f2024-04-22T19:39:51ZengDe Gruytere-Polymers1618-72292024-04-0124151410.1515/epoly-2023-0164Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE compositesMa Yulong0Yang Kang1Zhang Yi2Wang Juheng3Zeng Shu4Huang Xiaoxiao5Guizhou Institute of Metallurgy and Chemical Engineering, Guiyang, Guizhou, 550014, ChinaGuizhou Institute of Metallurgy and Chemical Engineering, Guiyang, Guizhou, 550014, ChinaGuizhou Institute of Metallurgy and Chemical Engineering, Guiyang, Guizhou, 550014, ChinaGuizhou Institute of Metallurgy and Chemical Engineering, Guiyang, Guizhou, 550014, ChinaGuizhou Institute of Metallurgy and Chemical Engineering, Guiyang, Guizhou, 550014, ChinaGuizhou Institute of Metallurgy and Chemical Engineering, Guiyang, Guizhou, 550014, ChinaThe heterogeneous nucleation process of polypropylene (PP)/high density polyethylene (HDPE)/thermoplastic elastomer (POE) composites was realized through blending modification, and characterization techniques, including scanning electron microscopy, differential scanning calorimetry, X-ray diffraction, and dynamic mechanical analysis, were used to analyze the pattern of the impact of modified dicyclohexyl-terephthalamide (TMB-5) on the mechanical properties and thermal stability of the PP/HDPE/POE composites. The results indicated that the modified TMB-5 was advantageous to the improvement of the mechanical properties and thermal stability of the high-temperature (cooking temperature)-resistant PP/HDPE/POE composites. When the amount of added modified TMB-5 was 0.4%, the impact strength and tensile strength of the PP/HDPE/POE composites increased to 36.3 kJ/m2 and 31.7 MPa, respectively, which were, respectively, 99.5% and 8.5% higher than those of the materials prepared when the amount of added modified TMB was 0.1%. The materials had higher storage modulus in room-temperature and high-temperature environments: 2,438.2 MPa (room temperature), 1,103.9 MPa (120°C), and 1,054.8 MPa (140°C). In addition, the capability of the PP/HDPE/POE composites to crystallize was improved continuously, and the crystallinity increased considerably. At the same time, the crystallization and melting temperatures increased, β-crystal formation was induced, and glass transition temperature increased, thus effectively improving the mechanical properties and thermal stability of the high-temperature (cooking temperature)-resistant PP/HDPE/POE composites.https://doi.org/10.1515/epoly-2023-0164polypropylenenucleating agent tmb-5storage modulusmechanical propertiesthermal stability |
| spellingShingle | Ma Yulong Yang Kang Zhang Yi Wang Juheng Zeng Shu Huang Xiaoxiao Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites e-Polymers polypropylene nucleating agent tmb-5 storage modulus mechanical properties thermal stability |
| title | Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites |
| title_full | Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites |
| title_fullStr | Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites |
| title_full_unstemmed | Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites |
| title_short | Mechanical properties and thermal stability of high-temperature (cooking temperature)-resistant PP/HDPE/POE composites |
| title_sort | mechanical properties and thermal stability of high temperature cooking temperature resistant pp hdpe poe composites |
| topic | polypropylene nucleating agent tmb-5 storage modulus mechanical properties thermal stability |
| url | https://doi.org/10.1515/epoly-2023-0164 |
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