Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection
The geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental...
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2020-07-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-020-17381-4 |
| _version_ | 1818423080902459392 |
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| author | Daofu Yuan Yin Huang Wentao Chen Hailin Zhao Shengrui Yu Chang Luo Yuxin Tan Siwen Wang Xingan Wang Zhigang Sun Xueming Yang |
| author_facet | Daofu Yuan Yin Huang Wentao Chen Hailin Zhao Shengrui Yu Chang Luo Yuxin Tan Siwen Wang Xingan Wang Zhigang Sun Xueming Yang |
| author_sort | Daofu Yuan |
| collection | DOAJ |
| description | The geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental evidence and insight into its origin. |
| first_indexed | 2024-12-14T13:36:28Z |
| format | Article |
| id | doaj.art-2045d474874846e6a42ffd08eff5c2ca |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-14T13:36:28Z |
| publishDate | 2020-07-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-2045d474874846e6a42ffd08eff5c2ca2022-12-21T22:59:34ZengNature PortfolioNature Communications2041-17232020-07-011111710.1038/s41467-020-17381-4Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersectionDaofu Yuan0Yin Huang1Wentao Chen2Hailin Zhao3Shengrui Yu4Chang Luo5Yuxin Tan6Siwen Wang7Xingan Wang8Zhigang Sun9Xueming Yang10Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of ChinaState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesHefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of ChinaState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesHangzhou Institute of Advanced Studies, Zhejiang Normal UniversityHefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of ChinaHefei National Laboratory for Physical Sciences at the Microscale and Department of Chemical Physics, University of Science and Technology of ChinaState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesState Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of SciencesThe geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental evidence and insight into its origin.https://doi.org/10.1038/s41467-020-17381-4 |
| spellingShingle | Daofu Yuan Yin Huang Wentao Chen Hailin Zhao Shengrui Yu Chang Luo Yuxin Tan Siwen Wang Xingan Wang Zhigang Sun Xueming Yang Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection Nature Communications |
| title | Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection |
| title_full | Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection |
| title_fullStr | Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection |
| title_full_unstemmed | Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection |
| title_short | Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection |
| title_sort | observation of the geometric phase effect in the h hd h2 d reaction below the conical intersection |
| url | https://doi.org/10.1038/s41467-020-17381-4 |
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