7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate
The title compound, C24H15BrO2S·0.5C6H6, crystallizes as a benzene hemisolvate. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the naphthofuran fragment, and the phenyl ring is almost perpendicular to the plane of the naphthofuran...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809025860 |
| _version_ | 1818913516561629184 |
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| author | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_facet | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee |
| author_sort | Hong Dae Choi |
| collection | DOAJ |
| description | The title compound, C24H15BrO2S·0.5C6H6, crystallizes as a benzene hemisolvate. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the naphthofuran fragment, and the phenyl ring is almost perpendicular to the plane of the naphthofuran fragment [83.78 (8)°] and is tilted slightly towards it. The 2-phenyl ring is rotated out of the naphthofuran plane by a dihedral angle of 25.2 (1)°. The crystal structure is stabilized by aromatic π–π interactions between the central benzene ring and the furan ring of the neighbouring naphthofuran systems [centroid–centroid distance = 3.611 (3) Å], and by intermolecular C—H...π interactions between the benzene H atom of the phenylsulfinyl substituent and the 2-phenyl ring of an adjacent molecule. In addition, the crystal structure exhibits a weak non-classical intermolecular C—H...O hydrogen bond. |
| first_indexed | 2024-12-19T23:31:44Z |
| format | Article |
| id | doaj.art-20543485b480455e82b253fa99b2667d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T23:31:44Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-20543485b480455e82b253fa99b2667d2022-12-21T20:01:43ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658o1812o181210.1107/S16005368090258607-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvateHong Dae ChoiPil Ja SeoByeng Wha SonUk LeeThe title compound, C24H15BrO2S·0.5C6H6, crystallizes as a benzene hemisolvate. The O atom and the phenyl group of the phenylsulfinyl substituent lie on opposite sides of the plane of the naphthofuran fragment, and the phenyl ring is almost perpendicular to the plane of the naphthofuran fragment [83.78 (8)°] and is tilted slightly towards it. The 2-phenyl ring is rotated out of the naphthofuran plane by a dihedral angle of 25.2 (1)°. The crystal structure is stabilized by aromatic π–π interactions between the central benzene ring and the furan ring of the neighbouring naphthofuran systems [centroid–centroid distance = 3.611 (3) Å], and by intermolecular C—H...π interactions between the benzene H atom of the phenylsulfinyl substituent and the 2-phenyl ring of an adjacent molecule. In addition, the crystal structure exhibits a weak non-classical intermolecular C—H...O hydrogen bond.http://scripts.iucr.org/cgi-bin/paper?S1600536809025860 |
| spellingShingle | Hong Dae Choi Pil Ja Seo Byeng Wha Son Uk Lee 7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate Acta Crystallographica Section E |
| title | 7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate |
| title_full | 7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate |
| title_fullStr | 7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate |
| title_full_unstemmed | 7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate |
| title_short | 7-Bromo-2-phenyl-1-(phenylsulfinyl)naphtho[2,1-b]furan benzene hemisolvate |
| title_sort | 7 bromo 2 phenyl 1 phenylsulfinyl naphtho 2 1 b furan benzene hemisolvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809025860 |
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