(3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium
The molecular structure of the title compound, [Al(CH3)2(C22H26NO)], displays a monomer with the AlIII atom in a distorted tetrahedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O—Al—N bite angle of the chelating...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2012-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536812005880 |
| _version_ | 1818322596399153152 |
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| author | Haijun Hao Baichun Zhu Jianjun Yi |
| author_facet | Haijun Hao Baichun Zhu Jianjun Yi |
| author_sort | Haijun Hao |
| collection | DOAJ |
| description | The molecular structure of the title compound, [Al(CH3)2(C22H26NO)], displays a monomer with the AlIII atom in a distorted tetrahedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O—Al—N bite angle of the chelating ligand is 94.14 (9)°. The O—C—C—C—N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak intermolecular C—H...O interactions are observed. |
| first_indexed | 2024-12-13T10:59:19Z |
| format | Article |
| id | doaj.art-205d91ac2ca348308072c37779b24f20 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-13T10:59:19Z |
| publishDate | 2012-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-205d91ac2ca348308072c37779b24f202022-12-21T23:49:19ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682012-04-01684m351m35210.1107/S1600536812005880(3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminiumHaijun HaoBaichun ZhuJianjun YiThe molecular structure of the title compound, [Al(CH3)2(C22H26NO)], displays a monomer with the AlIII atom in a distorted tetrahedral environment defined by two methyl groups and the N and O atoms of the chelating ketiminate anion. The O—Al—N bite angle of the chelating ligand is 94.14 (9)°. The O—C—C—C—N backbone of the ligand is nearly coplanar (r.m.s. deviation = 0.029 Å) and the Al atom deviates significantly from the mean plane by 0.525 (3) Å. In the crystal, weak intermolecular C—H...O interactions are observed.http://scripts.iucr.org/cgi-bin/paper?S1600536812005880 |
| spellingShingle | Haijun Hao Baichun Zhu Jianjun Yi (3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium Acta Crystallographica Section E |
| title | (3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium |
| title_full | (3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium |
| title_fullStr | (3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium |
| title_full_unstemmed | (3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium |
| title_short | (3-{[2,6-Bis(1-methylethyl)phenyl]imino-κN}-1-phenylbut-1-en-1-olato-κO)dimethylaluminium |
| title_sort | 3 2 6 bis 1 methylethyl phenyl imino amp 954 n 1 phenylbut 1 en 1 olato amp 954 o dimethylaluminium |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536812005880 |
| work_keys_str_mv | AT haijunhao 326bis1methylethylphenyliminoamp954n1phenylbut1en1olatoamp954odimethylaluminium AT baichunzhu 326bis1methylethylphenyliminoamp954n1phenylbut1en1olatoamp954odimethylaluminium AT jianjunyi 326bis1methylethylphenyliminoamp954n1phenylbut1en1olatoamp954odimethylaluminium |