Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol
Isoprenylation of aldehydes and ketones was directly performed by selective indium insertion on a mixture of 2-bromomethyl-1,3-butadiene and its vinylic isomers in good yields. A short synthesis of (±)-ipsenol, an aggregation pheromone of the Ips paraconfusus bark beetle, demonstrates the utility of...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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Sociedade Brasileira de Química
2003-01-01
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| Series: | Journal of the Brazilian Chemical Society |
| Subjects: | |
| Online Access: | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000500010 |
| _version_ | 1818648196198432768 |
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| author | Ceschi Marco A. Petzhold Cesar Schenato Rossana A. |
| author_facet | Ceschi Marco A. Petzhold Cesar Schenato Rossana A. |
| author_sort | Ceschi Marco A. |
| collection | DOAJ |
| description | Isoprenylation of aldehydes and ketones was directly performed by selective indium insertion on a mixture of 2-bromomethyl-1,3-butadiene and its vinylic isomers in good yields. A short synthesis of (±)-ipsenol, an aggregation pheromone of the Ips paraconfusus bark beetle, demonstrates the utility of this method in organic synthesis. |
| first_indexed | 2024-12-17T01:14:35Z |
| format | Article |
| id | doaj.art-20767d08ff5a4d2ebaeb5f0faa3bce1c |
| institution | Directory Open Access Journal |
| issn | 0103-5053 |
| language | English |
| last_indexed | 2024-12-17T01:14:35Z |
| publishDate | 2003-01-01 |
| publisher | Sociedade Brasileira de Química |
| record_format | Article |
| series | Journal of the Brazilian Chemical Society |
| spelling | doaj.art-20767d08ff5a4d2ebaeb5f0faa3bce1c2022-12-21T22:09:02ZengSociedade Brasileira de QuímicaJournal of the Brazilian Chemical Society0103-50532003-01-01145759763Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenolCeschi Marco A.Petzhold CesarSchenato Rossana A.Isoprenylation of aldehydes and ketones was directly performed by selective indium insertion on a mixture of 2-bromomethyl-1,3-butadiene and its vinylic isomers in good yields. A short synthesis of (±)-ipsenol, an aggregation pheromone of the Ips paraconfusus bark beetle, demonstrates the utility of this method in organic synthesis.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000500010isoprenylationindium2-bromomethyl-1,3-butadiene(±)-ipsenol |
| spellingShingle | Ceschi Marco A. Petzhold Cesar Schenato Rossana A. Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol Journal of the Brazilian Chemical Society isoprenylation indium 2-bromomethyl-1,3-butadiene (±)-ipsenol |
| title | Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol |
| title_full | Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol |
| title_fullStr | Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol |
| title_full_unstemmed | Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol |
| title_short | Indium mediated isoprenylation of carbonyl compounds with 2-bromomethyl-1,3-butadiene: a short synthesis of (±)-ipsenol |
| title_sort | indium mediated isoprenylation of carbonyl compounds with 2 bromomethyl 1 3 butadiene a short synthesis of ipsenol |
| topic | isoprenylation indium 2-bromomethyl-1,3-butadiene (±)-ipsenol |
| url | http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000500010 |
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