Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)]
In the title compound, [Co(NCS)2(C16H16N4O2)]n, the octahedrally coordinated CoII ion lies on a crystallographic inversion center, with trans isothiocyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetradentate bis(4-pyridylcarbonyl)piperazine (4-bpfp) ligands link the Co(NCS)...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2010-06-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053681001915X |
| _version_ | 1818945493745532928 |
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| author | Zachary M. Wilseck Robert L. LaDuca |
| author_facet | Zachary M. Wilseck Robert L. LaDuca |
| author_sort | Zachary M. Wilseck |
| collection | DOAJ |
| description | In the title compound, [Co(NCS)2(C16H16N4O2)]n, the octahedrally coordinated CoII ion lies on a crystallographic inversion center, with trans isothiocyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetradentate bis(4-pyridylcarbonyl)piperazine (4-bpfp) ligands link the Co(NCS)2 units into a [Co(NCS)2(4-bpfp)]n coordination polymer layer that is oriented parallel to (101). The layers stack along [010] to construct the pseudo-three-dimensional structure. |
| first_indexed | 2024-12-20T08:00:00Z |
| format | Article |
| id | doaj.art-209380c175a045278d5c231e0cde72b1 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T08:00:00Z |
| publishDate | 2010-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-209380c175a045278d5c231e0cde72b12022-12-21T19:47:32ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682010-06-01666m713m71310.1107/S160053681001915XPoly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)]Zachary M. WilseckRobert L. LaDucaIn the title compound, [Co(NCS)2(C16H16N4O2)]n, the octahedrally coordinated CoII ion lies on a crystallographic inversion center, with trans isothiocyanate ligands. Pyridyl N-donor atoms and formyl O-donor atoms from exotetradentate bis(4-pyridylcarbonyl)piperazine (4-bpfp) ligands link the Co(NCS)2 units into a [Co(NCS)2(4-bpfp)]n coordination polymer layer that is oriented parallel to (101). The layers stack along [010] to construct the pseudo-three-dimensional structure.http://scripts.iucr.org/cgi-bin/paper?S160053681001915X |
| spellingShingle | Zachary M. Wilseck Robert L. LaDuca Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)] Acta Crystallographica Section E |
| title | Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)] |
| title_full | Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)] |
| title_fullStr | Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)] |
| title_full_unstemmed | Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)] |
| title_short | Poly[[μ4-bis(4-pyridylcarbonyl)piperazine-κ4N:N′:O:O′]bis(thiocyanato-κN)cobalt(II)] |
| title_sort | poly amp 956 4 bis 4 pyridylcarbonyl piperazine amp 954 4n n amp 8242 o o amp 8242 bis thiocyanato amp 954 n cobalt ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053681001915X |
| work_keys_str_mv | AT zacharymwilseck polyamp9564bis4pyridylcarbonylpiperazineamp9544nnamp8242ooamp8242bisthiocyanatoamp954ncobaltii AT robertlladuca polyamp9564bis4pyridylcarbonylpiperazineamp9544nnamp8242ooamp8242bisthiocyanatoamp954ncobaltii |